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锻造温度和微弧涂层对AZ80镁合金静态/应力腐蚀抗性的影响

Effects of Forging Temperature and Micro-Arc Coatings on the Static/Stress Corrosion Resistance of AZ80 Magnesium Alloy.

作者信息

Xue Yuna, Zhang Jie, Shen Yi, Qiao Yongpeng, Luo Sheji, Wang Di

机构信息

School of Materials Science and Engineering, Xi'an Shiyou University, Xi'an 710065, China.

Xi'an Flit Heat Treatment Co., Ltd., Xi'an 710065, China.

出版信息

Materials (Basel). 2025 Jun 1;18(11):2590. doi: 10.3390/ma18112590.

DOI:10.3390/ma18112590
PMID:40508586
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12156218/
Abstract

To enhance the surface protection of exposed moving parts made from magnesium alloys, this study focuses on developing high-performance micro-arc composite (MCC) coatings on AZ80 wrought magnesium alloy substrate. AZ80 alloys were fabricated through forging at different temperatures (250 °C, 350 °C, and 450 °C) to investigate the influence of thermal deformation on substrate properties. Subsequently, micro-arc oxidation (MAO) coatings and MCC coatings were applied to the forged alloys. Comprehensive analyses-including microstructural characterization, salt spray corrosion tests, and stress corrosion cracking (SCC) evaluations-were conducted under both static and stress conditions. Among the forging temperatures, 250 °C produced substrates with refined grains and a favorable distribution of β-MgAl precipitates, resulting in improved baseline corrosion resistance. MAO coatings offered moderate protection, primarily delaying corrosion initiation and crack propagation under stress environments. Building upon this foundation, MCC coatings-fabricated by electrostatic spraying to form an inner-embedded and outer-wrapped structure over the MAO layer-demonstrated significantly superior protective performance. Under both static and stress corrosion scenarios, the MCC coatings effectively suppressed SCC initiation and progression, highlighting their potential for robust surface protection in demanding service environments.

摘要

为增强镁合金制成的外露运动部件的表面防护性能,本研究着重于在AZ80变形镁合金基体上开发高性能微弧复合(MCC)涂层。通过在不同温度(250°C、350°C和450°C)下锻造制备AZ80合金,以研究热变形对基体性能的影响。随后,将微弧氧化(MAO)涂层和MCC涂层应用于锻造合金。在静态和应力条件下进行了包括微观结构表征、盐雾腐蚀试验和应力腐蚀开裂(SCC)评估在内的综合分析。在锻造温度中,250°C锻造的基体晶粒细化,β-MgAl析出相分布良好,从而提高了基线耐蚀性。MAO涂层提供了适度的防护,主要是在应力环境下延迟了腐蚀起始和裂纹扩展。在此基础上,通过静电喷涂制备的MCC涂层在MAO层上形成了内埋外包结构,表现出显著优越的防护性能。在静态和应力腐蚀情况下,MCC涂层均有效抑制了SCC的起始和发展,突出了其在苛刻服役环境中实现强大表面防护的潜力。

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本文引用的文献

1
Predicting localised corrosion and mechanical performance of a PEO surface modified rare earth magnesium alloy for implant use through in-silico modelling.通过计算机模拟预测用于植入的微弧氧化表面改性稀土镁合金的局部腐蚀和力学性能。
Bioact Mater. 2023 Mar 21;26:437-451. doi: 10.1016/j.bioactmat.2023.03.009. eCollection 2023 Aug.
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In-vitro characterization of stress corrosion cracking of aluminium-free magnesium alloys for temporary bio-implant applications.用于临时生物植入应用的无铝镁合金应力腐蚀开裂的体外特性研究
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