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使用无机矿物水菱镁矿和菱镁矿制备新型阻燃木塑复合材料:电气工程应用方面

Novel Flame-Retardant Wood-Polymer Composites by Using Inorganic Mineral Huntite and Hydromagnesite: An Aspect of Application in Electrical Engineering.

作者信息

Atay Gül Yılmaz, Wilk-Jakubowski Jacek Lukasz, Loboichenko Valentyna

机构信息

Department of Metallurgical and Materials Engineering Çiğli, Izmir Katip Çelebi University, İzmir 35620, Turkey.

Department of Information Systems, Kielce University of Technology, 7 Tysiąclecia Państwa Polskiego Ave., 25-314 Kielce, Poland.

出版信息

Materials (Basel). 2025 Jun 5;18(11):2652. doi: 10.3390/ma18112652.

Abstract

In this study, a flame-retardant wood-polymer composite was produced using huntite-hydromagnesite mineral, recognized for its non- flammability properties. In this context, wood-polymer composites were produced with the co-rotating twin-screw extrusion technique, while polypropylene was applied as the composite matrix, medium density fiberboard waste and inorganic huntite-hydromagnesite mineral were used as the reinforcement material. The proportion of wood powder additives was changed to 10% and 20%, and the huntite and hydromagnesite ratio was changed to 30%, 40%, 50% and 60%. Maleic anhydride grafted polypropylene, i.e., MAPP, was applied as a binder at a rate of 3%. Polypropylene, wood fibers, mineral powders, and MAPP blended in the mixer were processed in the extruder and turned into granules. Structural, morphological, thermal, mechanical, and flame-retardant properties of the composites were analyzed using XRD, SEM, FTIR, TGA, tensile testing, and the UL-94 vertical flammability test. Test samples were prepared to evaluate the physical and mechanical properties with a compression molding machine. It was concluded that the composites gained significant flame retardancy with the addition of huntite hydromagnesite. The potential for using this material in various fields and its compliance with the principles of circular economy and the Sustainable Development Goals (SDG 12) were noted.

摘要

在本研究中,使用以其不燃性而闻名的碳酸镁钙镁石矿物制备了一种阻燃木塑复合材料。在此背景下,采用同向旋转双螺杆挤出技术制备木塑复合材料,以聚丙烯作为复合基体,中密度纤维板废料和无机碳酸镁钙镁石矿物作为增强材料。木粉添加剂的比例分别改为10%和20%,碳酸镁钙镁石的比例改为30%、40%、50%和60%。以3%的比例使用马来酸酐接枝聚丙烯(即MAPP)作为粘结剂。在混合机中混合的聚丙烯、木纤维、矿物粉末和MAPP在挤出机中加工成颗粒。使用X射线衍射(XRD)、扫描电子显微镜(SEM)、傅里叶变换红外光谱(FTIR)、热重分析(TGA)、拉伸试验和UL-94垂直燃烧试验对复合材料的结构、形态、热性能、力学性能和阻燃性能进行了分析。使用压缩成型机制备测试样品以评估其物理和力学性能。得出的结论是,添加碳酸镁钙镁石后复合材料获得了显著的阻燃性。指出了这种材料在各个领域的应用潜力及其符合循环经济原则和可持续发展目标(可持续发展目标12)的情况。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef92/12156906/435c5620b7a2/materials-18-02652-g001.jpg

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