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聚碳酸酯在屈服后循环试验中的非线性响应。

Nonlinear Response of a Polycarbonate in Post-Yield Cyclic Tests.

作者信息

Trejo Carrillo David, Díaz Díaz Alberto

机构信息

Centro de Investigación en Materiales Avanzados, S.C. (CIMAV), Av. Miguel de Cervantes #120, Complejo Industrial Chihuahua, Chihuahua C.P. 31136, Mexico.

出版信息

Polymers (Basel). 2025 May 31;17(11):1535. doi: 10.3390/polym17111535.

DOI:10.3390/polym17111535
PMID:40508778
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12156974/
Abstract

This paper aims to investigate the mechanical behavior of a polycarbonate through cyclic tensile, compression, and torsiontests atstrain rates that reduce viscous effects for this material. Measurements included axial and transverse strains for uniaxial tests and shear strains for torsion. Tensile tests exhibited nonlinear elasticity, ratcheting, and plasticity, accompanied by an increase in volumetric strain. Compression tests revealed nonlinear elasticity, with the surprising result of positive plastic axial and volumetric strains, accompanied by marginal transverse strains. Torsional tests showed an elastic but nonlinear relationship between shear stress and strain. In these latter tests, positive plastic volumetric strains were observed, which suggests that deviatoric stress can also induce volumetric plastic strains. These findings are of great importance for developing mathematical models of glassy amorphous polymers, and the observations contribute to understanding the complex behavior of such materials.

摘要

本文旨在通过循环拉伸、压缩和扭转试验,研究聚碳酸酯在降低该材料粘性效应的应变率下的力学行为。测量内容包括单轴试验的轴向和横向应变以及扭转试验的剪切应变。拉伸试验表现出非线性弹性、棘轮效应和塑性,同时体积应变增加。压缩试验揭示了非线性弹性,令人惊讶的是出现了正的塑性轴向应变和体积应变,同时伴有微小的横向应变。扭转试验表明剪切应力与应变之间存在弹性但非线性的关系。在这些后期试验中,观察到了正的塑性体积应变,这表明偏应力也可诱导体积塑性应变。这些发现对于建立玻璃态非晶态聚合物的数学模型非常重要,这些观察结果有助于理解此类材料的复杂行为。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/c7480e210535/polymers-17-01535-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/d0c5c54516c3/polymers-17-01535-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/90f37fdd68d5/polymers-17-01535-g007.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/5b9aaf8480ff/polymers-17-01535-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/07eb254d66d9/polymers-17-01535-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/fa51b3c14f6a/polymers-17-01535-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/39d34e46a727/polymers-17-01535-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/bde32209bb86/polymers-17-01535-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/89bd9360219a/polymers-17-01535-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/599d788cb431/polymers-17-01535-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/c7480e210535/polymers-17-01535-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/d0c5c54516c3/polymers-17-01535-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/23ef58a3b6f9/polymers-17-01535-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/31319226001d/polymers-17-01535-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/8e17648969ca/polymers-17-01535-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/d647dd68396f/polymers-17-01535-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/bfde17f3a3c5/polymers-17-01535-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/90f37fdd68d5/polymers-17-01535-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/058fbbbf2cb2/polymers-17-01535-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/5b9aaf8480ff/polymers-17-01535-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/07eb254d66d9/polymers-17-01535-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/fa51b3c14f6a/polymers-17-01535-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/6d8277192ff3/polymers-17-01535-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/39d34e46a727/polymers-17-01535-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/bde32209bb86/polymers-17-01535-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/89bd9360219a/polymers-17-01535-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/599d788cb431/polymers-17-01535-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db4e/12156974/c7480e210535/polymers-17-01535-g017.jpg

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本文引用的文献

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Strain Hardening During Uniaxial Compression of Polymer Glasses.聚合物玻璃单轴压缩过程中的应变硬化
ACS Macro Lett. 2014 Aug 19;3(8):784-787. doi: 10.1021/mz5004129. Epub 2014 Jul 24.
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Inelastic Behavior of Polyoxymethylene for Wide Strain Rate and Temperature Ranges: Constitutive Modeling and Identification.宽应变率和温度范围内聚甲醛的非弹性行为:本构模型与识别
Materials (Basel). 2021 Jul 1;14(13):3667. doi: 10.3390/ma14133667.
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Theory of aging, rejuvenation, and the nonequilibrium steady state in deformed polymer glasses.
变形聚合物玻璃中的老化、 rejuvenation理论以及非平衡稳态 。 注:这里“rejuvenation”不太明确准确含义,可能是特定领域术语,暂直译为“rejuvenation” ,可根据具体学科背景进一步准确翻译。
Phys Rev E Stat Nonlin Soft Matter Phys. 2010 Oct;82(4 Pt 1):041804. doi: 10.1103/PhysRevE.82.041804. Epub 2010 Oct 20.