Verde Raffaele, D'Amore Alberto, Grassia Luigi
Department of Engineering, University of Campania "Luigi Vanvitelli", Via Roma 29, 81031 Aversa, Italy.
Polymers (Basel). 2025 Jun 17;17(12):1674. doi: 10.3390/polym17121674.
This article analyzes the residual stresses generated during the curing process of thermoset composites. Specifically, a numerical procedure is developed and implemented in Ansys 18.0 to evaluate, at the micromechanical level, the residual stresses in a carbon epoxy composite that undergoes the process of curing. The viscoelastic behavior of the epoxy material is modeled using a formulation recently published by the same authors. It accounts for the concurrent effect of curing and structural relaxation on epoxy's relaxation times, assuming thermo-rheological and thermo-chemical simplicities. The model validated for the neat epoxy matrix is now tested against the composite application. Various representative volume element (RVE) arrangements and fiber fractions are examined. The proposed procedure can predict the evolution of mechanical properties (apparent stiffness and creep compliance) and the residual stresses that develop in each composite constituent during the cure. It demonstrates that the residual stresses in the matrix are a consistent fraction of an epoxy's nominal strength and significantly influence the transverse mechanical properties of the composite.
本文分析了热固性复合材料固化过程中产生的残余应力。具体而言,开发了一种数值程序并在Ansys 18.0中实现,以在微观力学层面评估经历固化过程的碳环氧复合材料中的残余应力。环氧材料的粘弹性行为采用同一作者最近发表的公式进行建模。该公式考虑了固化和结构松弛对环氧松弛时间的同时影响,假设热流变和热化学具有简单性。针对纯环氧基体验证的模型现在针对复合材料应用进行测试。研究了各种代表性体积单元(RVE)排列和纤维分数。所提出的程序可以预测固化过程中每种复合材料成分的力学性能(表观刚度和蠕变柔量)的演变以及产生的残余应力。结果表明,基体中的残余应力是环氧名义强度的一个恒定比例,并对复合材料的横向力学性能有显著影响。