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质子离子液体在磁场存在下对放电加工过程中排放的空气污染物气体的减排效果。

The effect of protic ionic liquid in the reduction of air contaminant gases emitted from electrical discharge machining in the presence of magnetic field.

作者信息

Karamzadeh Behnam, Shabgard Mohmmadreza, Gholipour Ahad, Shekaari Hemayat, Golmohammadi Behrang

机构信息

Department of Mechanical Engineering, University of Tabriz, Tabriz, Iran.

Department of Mechanical Engineering, Urmia University Technology, Urmia, Iran.

出版信息

Sci Rep. 2025 Jul 3;15(1):23778. doi: 10.1038/s41598-025-05185-9.

Abstract

This study investigates the emissions of CO, CO, NO, NO, SO, and HS during Electrical Discharge Machining (EDM) using protic ionic liquids (PILs) combined with a magnetic field, a novel approach to enhance environmental performance. Ethanolamine formate (MEA), diethanolamine acetate (DEA), and triethanolamine lactate (TEA) were added at 1 v/v% and 3 v/v% concentrations to kerosene dielectric, with a 300 G magnetic field applied at discharge energies of 30 µJ and 120 µJ. PILs significantly promote oxidation, converting incomplete combustion products (CO, HS) into fully oxidized forms (CO, SO). MEA exhibited the strongest effect, achieving the greatest reductions in CO and HS emissions. Higher PIL concentrations enhanced these effects, though benefits diminished at 120 µJ due to oxidation saturation. The magnetic field inhibited oxidation at 30 µJ, increasing CO and HS emissions, but enhanced complete combustion at 120 µJ, reducing CO and HS while increasing CO and SO. Nitrogen oxides showed complex responses, with NO increasing at higher energy under the magnetic field. These findings highlight the synergistic potential of PILs and magnetic fields in reducing harmful emissions during EDM, offering insights for optimizing sustainable machining processes.

摘要

本研究调查了在放电加工(EDM)过程中,使用质子离子液体(PILs)并结合磁场这一提高环境性能的新方法时,一氧化碳(CO)、二氧化碳(CO₂)、一氧化氮(NO)、二氧化氮(NO₂)、二氧化硫(SO₂)和硫化氢(H₂S)的排放情况。将甲酸乙醇胺(MEA)、乙酸二乙醇胺(DEA)和乳酸三乙醇胺(TEA)以1体积/体积%和3体积/体积%的浓度添加到煤油介质中,并在30微焦和120微焦的放电能量下施加300高斯的磁场。质子离子液体显著促进氧化,将不完全燃烧产物(CO、H₂S)转化为完全氧化的形式(CO₂、SO₂)。MEA表现出最强的效果,实现了CO和H₂S排放的最大减少。较高的质子离子液体浓度增强了这些效果,不过在120微焦时由于氧化饱和,效果有所减弱。在30微焦时磁场抑制氧化,增加了CO和H₂S的排放,但在120微焦时增强了完全燃烧,减少了CO和H₂S,同时增加了CO₂和SO₂。氮氧化物表现出复杂的响应,在磁场作用下,较高能量时NO增加。这些发现突出了质子离子液体和磁场在减少放电加工过程中有害排放方面的协同潜力,为优化可持续加工工艺提供了见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/69f3/12229679/3ff27eddbf13/41598_2025_5185_Fig1_HTML.jpg

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