Yasui Kyuichi
National Institute of Advanced Industrial Science and Technology (AIST), Nagoya 463-8560, Japan.
Materials (Basel). 2025 Jun 27;18(13):3058. doi: 10.3390/ma18133058.
It has been theoretically suggested that the de Broglie wavelength of Li ions could become longer than the Li atomic distance in solid electrolytes under coherent acoustic phonons at room temperature when thermal noise is sufficiently suppressed by them. This suggests that some quantum effect of Li ions (not electrons) could appear under this condition, which could possibly result in the superconductivity of Li ions (bosons) in solid electrolytes at room temperature. A lower frequency of coherent phonons is better for this possibility. A mechanism for the generation of coherent phonons by repetitive pulsed-laser irradiation or possibly by ultrasound irradiation using a transducer is also discussed.
从理论上讲,有人提出,当热噪声被相干声子充分抑制时,在室温下,固体电解质中锂离子的德布罗意波长可能会变得比锂原子间距更长。这表明,在这种条件下可能会出现锂离子(而非电子)的某些量子效应,这可能会导致固体电解质中的锂离子(玻色子)在室温下出现超导性。较低频率的相干声子更有利于这种可能性。本文还讨论了通过重复脉冲激光照射或可能通过使用换能器的超声照射来产生相干声子的机制。