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304不锈钢焊接接头在模拟淡水环境中的腐蚀行为及机理

Corrosion Behavior and Mechanism of 304 Stainless Steel Welded Joints in Simulated Freshwater Environment.

作者信息

Yu Yue, Wang Xiayan, Wei Shilong, Chen Zengyao, Wang Zhanhua, Li Mengnan, Liu Zhiyong

机构信息

Zhengzhou Yellow River Hydro Power Development General Company, Zhengzhou 459000, China.

Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China.

出版信息

Materials (Basel). 2025 Jun 28;18(13):3074. doi: 10.3390/ma18133074.

Abstract

This investigation examines the corrosion behavior and mechanisms of 304 stainless steel shielded metal arc welding (SMAW) and gas metal arc welding (GMAW) joints in the simulated reservoir environment through electrochemical testing, stress-free hanging specimens and U-bend specimen immersion experiments, and microstructural characterization. The electrochemical results demonstrate that both welded joints exhibit a superior corrosion resistance in this environment, with a sensitivity of intergranular corrosion (IGC) below 1% and a corrosion rate below 0.005 mm/a. Increasing chloride concentrations elevate the passivation current densities for both the base metal and welded joints. The immersion testing revealed that after 90 days of exposure across the investigated chloride concentrations (50-300 mg/L), all welded specimens maintained surface integrity with no visible corrosion. Furthermore, U-bend specimens demonstrated no evidence of stress corrosion cracking, confirming a low stress corrosion susceptibility.

摘要

本研究通过电化学测试、无应力悬挂试样和U型弯试样浸泡实验以及微观结构表征,考察了304不锈钢手工电弧焊(SMAW)和气体保护金属极电弧焊(GMAW)接头在模拟水库环境中的腐蚀行为及机理。电化学结果表明,两种焊接接头在该环境中均表现出优异的耐腐蚀性,晶间腐蚀(IGC)敏感性低于1%,腐蚀速率低于0.005 mm/a。氯化物浓度的增加会提高母材和焊接接头的钝化电流密度。浸泡试验表明,在研究的氯化物浓度(50 - 300 mg/L)下暴露90天后,所有焊接试样均保持表面完整性,无明显腐蚀。此外,U型弯试样未显示应力腐蚀开裂迹象,证实其应力腐蚀敏感性较低。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea06/12251300/e550400a3b89/materials-18-03074-g001.jpg

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