Reiser Alain, Schuh Christopher A
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA.
Department of Materials Science and Engineering, KTH Royal Institute of Technology, Stockholm, 114 28, Sweden.
Small. 2025 Sep;21(36):e2503014. doi: 10.1002/smll.202503014. Epub 2025 Jul 14.
The deposition of device-grade inorganic materials is one key challenge toward the implementation of additive manufacturing (AM) in microfabrication, and to that end, a broad range of physico-chemical principles has been explored for 3D fabrication with micro- and nanoscale resolution. Yet, for metals, a process that achieves material quality rivalling that of established thin-film deposition methods, and at the same time, has the potential to combine high throughput production with a broad palette of processable materials, is still lacking. Here, the kinetic, solid-state bonding of metal thin films for the additive assembly of high-purity, high-density metals with micrometer-scale precision is introduced. Indirect laser ablation accelerates micrometer-thick gold films to hundreds of meters per second without their heating or ablation. Their subsequent impact on the substrate above a critical velocity forms a permanent, metallic bond in the solid state. Stacked layers are of high density (>99%). By defining thin-film layers with established lithographic methods prior to launch, a variable feature size (2-50 µm), arbitrary shape of bonded layers, and parallel transfer of up to 36 independent film units in a single shot, is demonstrated. Thus, the solid-state kinetic bonding principle as a viable and potentially versatile route for micro-scale AM of metals is established.
器件级无机材料的沉积是微纳制造中实现增材制造(AM)的一个关键挑战,为此,人们已经探索了广泛的物理化学原理用于具有微米和纳米级分辨率的3D制造。然而,对于金属来说,一种既能实现与成熟薄膜沉积方法相媲美的材料质量,又能将高通量生产与多种可加工材料相结合的工艺仍然缺乏。在此,我们介绍了用于以微米级精度进行高纯度、高密度金属添加剂组装的金属薄膜的动力学固态键合。间接激光烧蚀将微米厚的金膜加速到每秒数百米,而不会对其进行加热或烧蚀。随后,它们以高于临界速度的速度撞击基板,在固态中形成永久性的金属键。堆叠层具有高密度(>99%)。通过在发射前用成熟的光刻方法定义薄膜层,展示了可变的特征尺寸(2-50 µm)和任意形状的键合层,并且单次可并行转移多达36个独立的薄膜单元。因此,确立了固态动力学键合原理作为一种可行且可能通用的金属微尺度增材制造途径。