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用于卓越储能应用的NiCoS/MoS/MWCNT混合电极增强的电化学性能

Enhanced Electrochemical Proficiency of NiCoS/MoS/MWCNT Hybrid Electrodes for Superior Energy Storage Applications.

作者信息

Subramani Saravanan, Tamilselvan Arun, Rajamanickam Govindaraj, Karuppannan Aravinth

机构信息

Department of Physics, SSN Research Centre, Sri Sivasubramaniya Nadar College of Engineering, Kalavakkam, Tamilnadu-603110, India.

出版信息

Langmuir. 2025 Jul 29;41(29):19550-19561. doi: 10.1021/acs.langmuir.5c02355. Epub 2025 Jul 18.

Abstract

The development of electrode materials with outstanding electrochemical performance is critical to meeting the demand for supercapacitors (SCs). Using metal sulfides with carbon-based materials is an efficient method to address the requirements for high-performance electrochemical energy storage. Here, we synthesize a NiCoS/MoS/MWCNT composite using a hydrothermal technique. The prepared electrode material's structural, surface morphology, chemical composition, and electrochemical characteristics were analyzed. The NiCoS/MoS/MWCNT composite has a higher specific capacitance of 1090 F/g at 1 A/g and excellent capacitance retention of 90% after 10,000 cycles. Furthermore, the asymmetric SC has been successfully assembled by utilizing activated carbon (AC) for the negative electrode and NiCoS/MoS/MWCNT for the positive electrode. The constructed NiCoS/MoS/MWCNT//AC asymmetric SC (ASC) has an excellent energy density (ED) of 23.73 Wh/kg and a power density (PD) of 749.5 W/kg at 1 A/g. The study found that the NiCoS/MoS/MWCNT composite is an attractive electrode compound for SCs.

摘要

开发具有出色电化学性能的电极材料对于满足超级电容器(SCs)的需求至关重要。将金属硫化物与碳基材料结合使用是满足高性能电化学储能要求的有效方法。在此,我们采用水热技术合成了NiCoS/MoS/MWCNT复合材料。对制备的电极材料的结构、表面形貌、化学成分和电化学特性进行了分析。NiCoS/MoS/MWCNT复合材料在1 A/g时具有1090 F/g的较高比电容,在10000次循环后具有90%的优异电容保持率。此外,通过使用活性炭(AC)作为负极和NiCoS/MoS/MWCNT作为正极,成功组装了非对称超级电容器。构建的NiCoS/MoS/MWCNT//AC非对称超级电容器(ASC)在1 A/g时具有23.73 Wh/kg的优异能量密度(ED)和749.5 W/kg的功率密度(PD)。研究发现,NiCoS/MoS/MWCNT复合材料是一种有吸引力的超级电容器电极化合物。

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