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一种用于化妆品包装应用的新型全生物基材料复合材料。

A novel fully biobased material composite for cosmetic packaging applications.

作者信息

Santos Fátima, Rodrigues Pedro, Vargas Patrício, Massano Anabela, Oliveira Luís Miguel, Batista Catarina, Cruz Vasco, Mateus Artur, Mitchell Geoffrey R, Sobral Abílio J F N, Encarnação Telma

机构信息

PTScience, Alcobaça, 2460-060, Portugal.

Coimbra Chemistry Centre-Institute of Molecular Sciences (CQC-IMS), Department of Chemistry, University of Coimbra, Coimbra, 3004-535, Portugal.

出版信息

Sci Rep. 2025 Jul 24;15(1):26882. doi: 10.1038/s41598-025-10426-y.

Abstract

The extensive production and use of fossil-based plastics have led to their ubiquity worldwide, causing growing concern and environmental problems. Consequently, developing biobased polymers and biobased composite materials, aligned with circular economy principles, is now the focus as a sustainable alternative to fossil-based plastics. This work aimed to develop and characterise a new, fully biobased, and biodegradable material composite with properties similar to traditional fossil-based plastics, allowing its use in cosmetic product applications as an alternative to commonly used fossil-based plastics. A novel biobased composite comprising poly(3-hydroxybutyrate-co-3-hydroxyvalerate (PHBV), polylactic acid (PLA) chitosan (CS), acetyl tributyl citrate (ATBC) plant essential oils, and phycocyanin was successfully developed and processed using various techniques confirming its processability and versatility. Characterisation of the developed composites showed a reduction in mechanical properties with the addition of ATBC, essential oil and phycocyanin, with tensile results within the typical behaviour for PP (polypropylene) and PE (polyethylene). The thermal properties of the developed composites showed working temperatures in the same range as PP and PE. The results obtained are promising and, to the best of our knowledge, this work presents the first green material composite comprising PHBV, PLA, CS, essential oil, ATBC, and phycocyanin specifically designed for cosmetic packaging as a sustainable alternative to fossil-based plastics.

摘要

基于化石的塑料的广泛生产和使用已导致其在全球无处不在,引发了越来越多的关注和环境问题。因此,开发符合循环经济原则的生物基聚合物和生物基复合材料,作为基于化石的塑料的可持续替代品,已成为当前的重点。这项工作旨在开发和表征一种新型的、完全生物基且可生物降解的材料复合材料,其性能与传统的基于化石的塑料相似,以便在化妆品应用中替代常用的基于化石的塑料。一种新型生物基复合材料成功开发并通过各种技术进行了加工,该复合材料包含聚(3-羟基丁酸酯-共-3-羟基戊酸酯)(PHBV)、聚乳酸(PLA)、壳聚糖(CS)、乙酰柠檬酸三丁酯(ATBC)、植物精油和藻蓝蛋白,证实了其可加工性和多功能性。对所开发复合材料的表征表明,添加ATBC、精油和藻蓝蛋白后机械性能有所降低,拉伸结果在聚丙烯(PP)和聚乙烯(PE)的典型范围内。所开发复合材料的热性能表明其工作温度与PP和PE相同。所获得的结果很有前景,据我们所知,这项工作展示了第一种专门为化妆品包装设计的绿色材料复合材料,它由PHBV、PLA、CS、精油、ATBC和藻蓝蛋白组成,可作为基于化石的塑料的可持续替代品。

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