• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

用于可穿戴超级电容器的自修复、高拉伸性双网络凝胶聚合物电解质的设计与评估

Design and Evaluation of a Self-Healing, Highly Stretchable Double-Network Gel Polymer Electrolyte for Potential Use in Wearable Supercapacitors.

作者信息

Shodmanov Jasur, Qin Gang, Boymirzayev Azamat, Ibragimov Muzaffar, Ovodok Evgeni, Feng Yu

机构信息

Department of Metrology, Standardization and Management of Quality, Namangan State Technical University, Namangan 160110, Uzbekistan.

School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo, Henan 454003, China.

出版信息

ACS Omega. 2025 Jul 16;10(29):32476-32485. doi: 10.1021/acsomega.5c05335. eCollection 2025 Jul 29.

DOI:10.1021/acsomega.5c05335
PMID:40757319
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12311860/
Abstract

This work reports the design and synthesis of a novel self-healing and stretchable gel polymer electrolyte (GPE) based on a double-network (DN) architecture combining polyacrylamide (PAM) and gellan gum (GG). The GPE was fabricated via a UV-initiated one-pot photopolymerization process in the presence of Na ions, which act both as ionic charge carriers and physical cross-linkers through electrostatic interactions. The optimized PG-3 DN GPE exhibited remarkable mechanical performance, achieving a tensile strength of 2.0 MPa and an elongation at break of 400%. Furthermore, the GPE demonstrated high ionic conductivity (0.29 S/cm) and excellent self-healing efficiency (>90%) at 60 °C under ambient pressure, without the need for additional healing agents. Spectroscopic and morphological characterizations (FTIR, XPS, C NMR, SEM) confirmed the formation of a homogeneous and interconnected porous network that supports efficient ion mobility and structural integrity. The observed improvements in mechanical and electrochemical behavior were attributed to synergistic hydrogen bonding, Na-mediated ionic bridging, and optimized water retention. Compared to conventional GPEs, this PAM/GG-based DN system provides an environmentally friendly, biopolymer-integrated, and scalable platform suitable for next-generation flexible and wearable energy storage applications, particularly in supercapacitors.

摘要

这项工作报道了一种基于聚丙烯酰胺（PAM）和结冷胶（GG）双网络（DN）结构的新型自愈合可拉伸凝胶聚合物电解质（GPE）的设计与合成。该GPE是在钠离子存在下通过紫外光引发的一锅法光聚合工艺制备的，钠离子通过静电相互作用既作为离子电荷载体又作为物理交联剂。优化后的PG-3 DN GPE表现出卓越的机械性能，拉伸强度达到2.0 MPa，断裂伸长率为400%。此外，该GPE在环境压力下60°C时展现出高离子电导率（0.29 S/cm）和优异的自愈合效率（>90%），无需额外的愈合剂。光谱和形态表征（FTIR、XPS、C NMR、SEM）证实形成了均匀且相互连接的多孔网络，该网络支持高效的离子迁移和结构完整性。观察到的机械和电化学行为的改善归因于协同氢键、钠介导的离子桥接以及优化的保水性能。与传统GPE相比，这种基于PAM/GG的DN体系提供了一个环境友好、生物聚合物集成且可扩展的平台，适用于下一代柔性和可穿戴储能应用，特别是在超级电容器方面。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/188bba79b8e5/ao5c05335_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/ea9e6adf4a63/ao5c05335_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/c5a9d95b35e3/ao5c05335_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/0a41a7f79da7/ao5c05335_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/3e097b3708c9/ao5c05335_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/b84abea19d61/ao5c05335_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/10b4804a63a6/ao5c05335_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/dd021702fa4c/ao5c05335_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/188bba79b8e5/ao5c05335_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/ea9e6adf4a63/ao5c05335_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/c5a9d95b35e3/ao5c05335_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/0a41a7f79da7/ao5c05335_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/3e097b3708c9/ao5c05335_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/b84abea19d61/ao5c05335_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/10b4804a63a6/ao5c05335_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/dd021702fa4c/ao5c05335_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02f7/12311860/188bba79b8e5/ao5c05335_0008.jpg

相似文献

1
Design and Evaluation of a Self-Healing, Highly Stretchable Double-Network Gel Polymer Electrolyte for Potential Use in Wearable Supercapacitors.用于可穿戴超级电容器的自修复、高拉伸性双网络凝胶聚合物电解质的设计与评估
ACS Omega. 2025 Jul 16;10(29):32476-32485. doi: 10.1021/acsomega.5c05335. eCollection 2025 Jul 29.
2
Prescription of Controlled Substances: Benefits and Risks管制药品的处方：益处与风险
3
Poly(acrylic acid)-Based Composite Gel Polymer Electrolytes with High Mechanical Strength and Ionic Conductivity toward Flexible Zinc-Air Batteries with Long Cycling Lifetime.具有高机械强度和离子电导率的聚丙烯酸基复合凝胶聚合物电解质用于长循环寿命的柔性锌空气电池
ACS Appl Mater Interfaces. 2022 Oct 27. doi: 10.1021/acsami.2c14470.
4
Anion-Immobilized Gel Polymer Electrolyte with a High Ion Transference Number for High-Performance Lithium/Sodium Metal Batteries.用于高性能锂/钠金属电池的具有高离子迁移数的阴离子固定凝胶聚合物电解质
ACS Appl Mater Interfaces. 2023 Dec 2. doi: 10.1021/acsami.3c13883.
5
High-Voltage Lithium Batteries Enabled by Facile In Situ Fabrication of Monophasic Cellulose-Based Single-Ion Conductors.通过简便原位制备单相纤维素基单离子导体实现的高压锂电池。
ACS Appl Mater Interfaces. 2025 Jul 2;17(26):38131-38142. doi: 10.1021/acsami.5c07304. Epub 2025 Jun 18.
6
Electrophoresis电泳
7
Redox-Additive Gel Polymer Electrolyte Based on the Biodegradable Polymer Pectin for Supercapacitors with Enhanced Thermal Stability.基于可生物降解聚合物果胶的氧化还原添加剂凝胶聚合物电解质用于具有增强热稳定性的超级电容器。
ACS Appl Energy Mater. 2025 Jun 22;8(13):9391-9406. doi: 10.1021/acsaem.5c01039. eCollection 2025 Jul 14.
8
Natural Polysaccharide Strengthened Hydrogel Electrolyte and Biopolymer Derived Carbon for Durable Aqueous Zinc Ion Storage.用于耐用水系锌离子存储的天然多糖增强水凝胶电解质和生物聚合物衍生碳
ACS Appl Mater Interfaces. 2022 May 12. doi: 10.1021/acsami.2c03323.
9
Modulating Phase Separation via Multiple Hydrogen Bonding in Polyurethane-Based Gel Polymer Electrolytes for All-Solid-State Supercapacitors.通过多重氢键作用调控基于聚氨酯的凝胶聚合物电解质中的相分离用于全固态超级电容器
Small Methods. 2025 Jul 1:e2500881. doi: 10.1002/smtd.202500881.
10
[Preparation and chromatographic performance evaluation of hydrophilic interaction chromatography stationary phase based on amino acids].基于氨基酸的亲水作用色谱固定相的制备及色谱性能评价
Se Pu. 2025 Jul;43(7):734-743. doi: 10.3724/SP.J.1123.2025.04015.

本文引用的文献

1
One-Pot Synthesis of a Double-Network Hydrogel Electrolyte with Extraordinarily Excellent Mechanical Properties for a Highly Compressible and Bendable Flexible Supercapacitor.一锅法合成具有优异机械性能的双网络水凝胶电解质用于高可压缩和可弯曲的柔性超级电容器。
ACS Appl Mater Interfaces. 2018 Sep 5;10(35):29684-29693. doi: 10.1021/acsami.8b11377. Epub 2018 Aug 22.
2
Rationally Designed Self-Healing Hydrogel Electrolyte toward a Smart and Sustainable Supercapacitor.理性设计的自修复水凝胶电解质用于智能和可持续的超级电容器。
ACS Appl Mater Interfaces. 2017 Aug 23;9(33):27745-27753. doi: 10.1021/acsami.7b07836. Epub 2017 Aug 15.
3
Flexible and Self-Healing Aqueous Supercapacitors for Low Temperature Applications: Polyampholyte Gel Electrolytes with Biochar Electrodes.
用于低温应用的灵活自修复水系超级电容器：具有生物炭电极的聚两性电解质凝胶电解质。
Sci Rep. 2017 May 10;7(1):1685. doi: 10.1038/s41598-017-01873-3.
4
Fabrication of nanotweezers and their remote actuation by magnetic fields.纳米镊子的制造及其通过磁场的远程驱动。
Sci Rep. 2017 Mar 27;7(1):451. doi: 10.1038/s41598-017-00537-6.
5
Hydrogel: Preparation, characterization, and applications: A review.水凝胶：制备、表征和应用：综述。
J Adv Res. 2015 Mar;6(2):105-21. doi: 10.1016/j.jare.2013.07.006. Epub 2013 Jul 18.
6
A biodegradable gel electrolyte for use in high-performance flexible supercapacitors.一种用于高性能柔性超级电容器的可生物降解凝胶电解质。
ACS Appl Mater Interfaces. 2015 Feb 18;7(6):3503-11. doi: 10.1021/am5070987. Epub 2015 Feb 4.
7
Flexible solid-state supercapacitors based on three-dimensional graphene hydrogel films.基于三维石墨烯水凝胶薄膜的柔性固态超级电容器。
ACS Nano. 2013 May 28;7(5):4042-9. doi: 10.1021/nn4000836. Epub 2013 Apr 11.
8
Building better batteries.制造更好的电池。
Nature. 2008 Feb 7;451(7179):652-7. doi: 10.1038/451652a.