Ye Zhilong, Zou Niuniu, Zhang Daquan, Chen Yi, Yin Yuanyan, Feng Xia, Du Wei
College of Resources and Environmental Engineering, Guizhou University, Guiyang 550025, China.
Key Laboratory of Karst Georesources and Environment, Ministry of Education, Guizhou University, Guiyang 550025, China.
ACS Omega. 2025 Jul 16;10(29):31854-31867. doi: 10.1021/acsomega.5c03141. eCollection 2025 Jul 29.
The purpose of this research was to examine the paleoenvironment, hydrothermal activity, and restriction water condition of the Lower Cambrian Niutitang Formation shale gas reservoir in northern Guizhou and analyze the controlling factors for organic matter enrichment. This investigation is based on the geochemical analyses of the total organic carbon (TOC) and major and trace elements from drill core samples of YF1 Well in Fenggang Area, Northern Guizhou. TOC of the Niutitang Formation is mainly distributed between 0.21 and 2.47%. Redox environment indicators (such as V/(V + Ni), V/Cr, and Mo vs U) suggest an anoxic-reducing sedimentary background; water restriction condition indicators (Mo/TOC and Mo-TOC) reveal weakly to moderately restricted water body characteristics; terrigenous debris indicators (Ti/Al and CIA) indicate a gradual increase in terrigenous input under the context of weak chemical weathering; hydrothermal activity indicators (Sr/Ba and Co × Mn) disclose moderate-to-strong hydrothermal influence and weak upwelling influence; and paleoproductivity indicators (biogenic Ba (Ba), biogenic Ni (Ni), and P/Ti) collectively point to high biological productivity. Thus, nutrients introduced by hydrothermal activity establish the material basis for high biological productivity, anoxic-sulfidic environments and weakly to moderately restricted water bodies collectively inhibit organic matter decomposition, and enhanced terrigenous input promotes organic matter sedimentation and preservation. These factors jointly constitute an integrated control framework for organic matter enrichment.
本研究旨在考察黔北下寒武统牛蹄塘组页岩气储层的古环境、热液活动及水体限制条件,并分析有机质富集的控制因素。本研究基于对黔北凤冈地区YF1井岩芯样品的总有机碳(TOC)以及主微量元素的地球化学分析。牛蹄塘组的TOC主要分布在0.21%至2.47%之间。氧化还原环境指标(如V/(V + Ni)、V/Cr和Mo与U的比值)表明沉积背景为缺氧-还原环境;水体限制条件指标(Mo/TOC和Mo-TOC)显示水体特征为弱至中度受限;陆源碎屑指标(Ti/Al和CIA)表明在弱化学风化背景下陆源输入逐渐增加;热液活动指标(Sr/Ba和Co×Mn)揭示了中等到强烈的热液影响以及微弱的上升流影响;古生产力指标(生物源Ba(Ba)、生物源Ni(Ni)和P/Ti)共同表明生物生产力较高。因此,热液活动引入的营养物质为高生物生产力奠定了物质基础,缺氧-硫化环境以及弱至中度受限水体共同抑制了有机质分解,而陆源输入增加促进了有机质的沉积和保存。这些因素共同构成了有机质富集的综合控制框架。