Reeve Cameron P, Williamson Connor, Shelton Evan, Stace Anthony J, Besley Elena
School of Chemistry, University of Nottingham, Nottingham NG7 2RD, U.K.
J Phys Chem A. 2025 Aug 14;129(32):7461-7469. doi: 10.1021/acs.jpca.5c02515. Epub 2025 Aug 5.
Extreme atmospheric environments are often characterized by scorching temperatures and high densities of charged, polarizable particles. This study investigates two distinctly different extreme environments, volcanic ash plumes and the Venusian atmosphere, where the influence of particle polarization plays a pivotal role in driving electrostatic aggregation, particularly through like-charge attraction at small separations, which is often neglected by conventional models. In these conditions, accounting for complex polarization effects increases the estimation of collision efficiency and collision cross section by up to 25% as well as reduces the value of the velocity critical for aggregation by up to 30%, as compared to predictions by Coulomb's Law and the hard-sphere limit. These insights have wide-ranging implications for modeling charged particle dynamics in broader industrial, atmospheric, and astrophysical contexts.
极端大气环境通常具有酷热的温度和高密度的带电、可极化粒子。本研究调查了两种截然不同的极端环境,即火山灰羽流和金星大气层,在这些环境中,粒子极化的影响在驱动静电聚集方面起着关键作用,特别是通过小间距时的同电荷吸引,而传统模型往往忽略了这一点。在这些条件下,与库仑定律和硬球极限的预测相比,考虑复杂的极化效应可使碰撞效率和碰撞截面的估计值提高多达25%,并使聚集所需的临界速度值降低多达30%。这些见解对于在更广泛的工业、大气和天体物理背景下模拟带电粒子动力学具有广泛的意义。