Amine-modified waste tires for CO capture and resource utilization.

In this study, waste tires (WTs) were chosen to prepare an adsorbent material for carbon dioxide (CO) capture to reduce their huge amount of waste. To improve the CO selectivity, the WT powder was amine-modified using tetraethylenepentamine (TEPA) or polyethyleneimine at different loading levels [2.5, 5, 10, and 15% (w/w)]. The optimum condition to develop a high-performance CO adsorbent material was found to be the use of 10% (w/w) TEPA-modified WT (WT10T) with a CO flow rate of 70 mL min under ambient temperature and atmospheric pressure. Based on the kinetic study of WT10T, Avrami's model fitted well with the experimental data, suggesting both physisorption and chemisorption of the CO. When desorbed at 60 °C under vacuum pressure, the WT10T showed a reusability of more than 10 successive adsorption cycles. Additionally, the adsorbed CO in WT10T could be directly converted to value-added chemicals or fuels, such as ethylene, methane, carbon monoxide, and hydrogen, via an electrochemical reaction. Accordingly, this study shows a challenging way on how to both utilize waste materials as adsorbents and reduce the WT level from rubber industries.