Xu Rui, Li Baiyu, Liu Xiaokang, Peng Ben, Lu Guanghua, Yue Changsheng, Zhang Lei
School of Materials Science and Engineering, Tianjin Chengjian University, Tianjin 300384, China.
Tianjin Key Laboratory of Building Green Functional Materials, Tianjin Chengjian University, Tianjin 300384, China.
Materials (Basel). 2025 Aug 1;18(15):3619. doi: 10.3390/ma18153619.
In marine engineering applications, substituting conventional crushed stone coarse aggregates with coral aggregates offers dual advantages: reduced terrestrial quarrying operations and minimized construction material transportation costs. However, the inherent characteristics of coral aggregates-low bulk density, high porosity, and elevated water absorption capacity-adversely influence concrete workability and mechanical performance. To address these limitations, this investigation employed microbial-induced carbonate precipitation (MICP) for aggregate modification. The experimental design systematically evaluated the impacts of substrate concentration (1 mol/L) and mineralization period (14 days) on three critical parameters, mass gain percentage, water absorption reduction, and apparent density enhancement, across distinct particle size fractions (4.75-9.5 mm, 9.5-20 mm) and density classifications. Subsequent application trials assessed the performance of MICP-treated aggregates in marine concrete formulations. Results indicated that under a substrate concentration of 1 mol/L and mineralization period of 14 days, lightweight coral aggregates and coral aggregates within the 4.75-9.5 mm size fraction exhibited favorable modification effects. Specifically, their mass gain rates reached 11.75% and 11.22%, respectively, while their water absorption rates decreased by 32.22% and 34.75%, respectively. Apparent density increased from initial values of 1764 kg/m and 1930 kg/m to 2050 kg/m and 2207 kg/m. Concrete mixtures incorporating modified aggregates exhibited enhanced workability and strength improvement at all curing ages. The 28-day compressive strengths reached 62.1 MPa (11.69% increment), 46.2 MPa (6.94% increment), and 60.1 MPa (14.91% increment) for the 4.75-9.5 mm, 9.5-20 mm, and continuous grading groups, respectively, compared to untreated counterparts.