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通过在蒸汽氛围中进行热改性提高泡桐木材的功能和视觉特性

Enhancing Functional and Visual Properties of Paulownia Wood Through Thermal Modification in a Steam Atmosphere.

作者信息

Doczekalska Beata, Stachowiak-Wencek Agata, Bujnowicz Krzysztof, Sydor Maciej

机构信息

Department of Chemical Wood Technology, Faculty of Forestry and Wood Technology, Poznań University of Life Sciences, ul. Wojska Polskiego 38/42, 60-637 Poznań, Poland.

Institute of Natural Fibers & Medicinal Plants-National Research Institute, ul. Wojska Polskiego 71B, 60-630 Poznań, Poland.

出版信息

Polymers (Basel). 2025 Jul 22;17(15):2000. doi: 10.3390/polym17152000.

DOI:10.3390/polym17152000
PMID:40808050
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12349047/
Abstract

wood is characterized by rapid mass gain, but its limited mechanical strength hinders engineering applications. This study aimed to determine the effect of thermal modification in a steam atmosphere (at temperatures of 180 °C and 190 °C for 12 or 6 h with 3 or 6 h of steam dosing) on wood's selected physicochemical and aesthetic properties. Color changes (CIELAB), chemical composition (FTIR), density, and compressive strength parallel to the grain were evaluated. The results showed a clear darkening of the wood, a shift in hues towards red and yellow, and an increase in color saturation depending on the treatment parameters. FTIR spectroscopy confirmed a reduction in hydroxyl and carbonyl groups, indicating thermal degradation of hemicelluloses and extractives. Wood density remained relatively stable, despite observed mass losses and reduced swelling. The most significant increase in compressive strength, reaching 27%, was achieved after 6 h of modification at 180 °C with a concurrent 6 h steam dosing time. The obtained results confirm that thermal treatment can effectively improve the functional and visual properties of paulownia wood, favoring its broader application in the furniture and construction industries.

摘要

木材的特点是质量快速增加,但其有限的机械强度阻碍了工程应用。本研究旨在确定在蒸汽气氛中进行热改性(在180°C和190°C的温度下分别处理12小时或6小时,并分别进行3小时或6小时的蒸汽注入)对木材选定的物理化学和美学性能的影响。评估了颜色变化(CIELAB)、化学成分(FTIR)、密度以及与木纹平行的抗压强度。结果表明,木材明显变黑,色调向红色和黄色偏移,并且根据处理参数,颜色饱和度增加。FTIR光谱证实了羟基和羰基的减少,表明半纤维素和提取物发生了热降解。尽管观察到质量损失和膨胀减少,但木材密度保持相对稳定。在180°C下改性6小时并同时进行6小时蒸汽注入后,抗压强度提高最为显著,达到了27%。所得结果证实,热处理可以有效改善泡桐木材的功能和视觉性能,有利于其在家具和建筑行业更广泛的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/70452248cbc4/polymers-17-02000-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/3a5fead4631e/polymers-17-02000-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/db552e384a08/polymers-17-02000-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/c42a4da73dfc/polymers-17-02000-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/8799174571c6/polymers-17-02000-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/3fc297d92348/polymers-17-02000-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/70452248cbc4/polymers-17-02000-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/3a5fead4631e/polymers-17-02000-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/db552e384a08/polymers-17-02000-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/c42a4da73dfc/polymers-17-02000-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/8799174571c6/polymers-17-02000-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/3fc297d92348/polymers-17-02000-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ac6/12349047/70452248cbc4/polymers-17-02000-g006.jpg

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本文引用的文献

1
Oil Heat Treatment of Wood-A Comprehensive Analysis of Physical, Chemical, and Mechanical Modifications.木材的油热处理——物理、化学和力学改性的综合分析
Materials (Basel). 2024 May 16;17(10):2394. doi: 10.3390/ma17102394.
2
Durability of heat-treated Paulownia tomentosa and Pinus koraiensis woods in palm oil and air against brown- and white-rot fungi.热处理后的泡桐和红松木材在棕榈油和空气中对褐腐菌和白腐菌的耐久性。
Sci Rep. 2023 Dec 11;13(1):21929. doi: 10.1038/s41598-023-48971-z.
3
Radial Variability of Selected Physical and Mechanical Parameters of Juvenile Paulownia Wood from Extensive Cultivation in Central Europe-Case Study.
中欧大规模种植的幼龄泡桐木材选定物理和力学参数的径向变异性——案例研究
Materials (Basel). 2023 Mar 25;16(7):2615. doi: 10.3390/ma16072615.
4
Experimental Study on the Bending and Shear Behaviors of Chinese Paulownia Wood at Elevated Temperatures.高温下泡桐木材弯曲与剪切性能的试验研究
Polymers (Basel). 2022 Dec 18;14(24):5545. doi: 10.3390/polym14245545.
5
Some technological properties and uses of paulownia (Paulownia tomentosa Steud.) wood.泡桐(毛泡桐)木材的一些技术特性及用途。
J Environ Biol. 2010 May;31(3):351-5.
6
Spectral characterization of eucalyptus wood.桉木的光谱特征
Appl Spectrosc. 2007 Nov;61(11):1168-77. doi: 10.1366/000370207782597076.