Rahimi Najmeh, Sehrish Saba, Akompong Samuel K, Barnes Bayler G, Windorff Cory J, Talipov Marat R, Tello-Aburto Rodolfo
Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, NM, USA.
Org Biomol Chem. 2025 Aug 27;23(34):7719-7723. doi: 10.1039/d5ob00663e.
A novel, annulative endoperoxidation of tetronate derivatives bearing unsaturated side chains is presented. The reaction requires a simple setup and proceeds under mild conditions to generate tricyclic endoperoxides in modest diastereoselectivities and useful yields. A free-radical mechanism is proposed.
本文报道了一种新型的、带有不饱和侧链的特窗酸衍生物的环化内过氧化物反应。该反应装置简单，在温和条件下进行，以适度的非对映选择性和良好的产率生成三环内过氧化物。提出了一种自由基机理。
