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生物质衍生碳点:制备、性质及应用

Biomass-Derived Carbon Dots: Preparation, Properties, and Applications.

作者信息

Liu Qinfeng, Chen Huan, Mi Ruiyu, Min Xin, Fang Minghao, Wu Xiaowen, Huang Zhaohui, Liu Yangai

机构信息

Engineering Research Center of Ministry of Education for Geological Carbon Storage and Low Carbon Utilization of Resources, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China.

出版信息

Nanomaterials (Basel). 2025 Aug 19;15(16):1279. doi: 10.3390/nano15161279.

DOI:10.3390/nano15161279
PMID:40863859
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12389206/
Abstract

With the intensification of the global energy crisis, green, low-carbon, and environmentally friendly biomass materials have become the focus of research. Among them, biomass-derived carbon dots (B-CDs), a novel class of sustainable zero-dimensional carbon nanomaterials, attract significant interest due to their environmental friendliness, low toxicity, and unique optical properties. Research findings indicate that B-CDs, utilizing biomass materials as carbon sources, demonstrate significant potential in numerous application fields through structural design and photo-functionalization. However, the underlying mechanisms and formation processes of B-CDs remain inadequately elucidated, and systematic summarization still requires further refinement. Therefore, this review systematically summarizes the synthesis methods, precursor structures, formation mechanisms, luminescent properties, and prevailing applications of B-CDs, with a particular emphasis on recent advances in their use for sensing, anti-counterfeiting, bioimaging, and optronics. In addition, the challenges encountered in performance-oriented controllable preparation and large-scale production were also clarified. This comprehensive review provides a theoretical foundation for further research and multidisciplinary applications of B-CDs, thereby contributing to promoting large-scale commercialization and industrial implementation.

摘要

随着全球能源危机的加剧,绿色、低碳、环保的生物质材料已成为研究热点。其中,生物质衍生碳点(B-CDs)作为一类新型的可持续零维碳纳米材料,因其环境友好、低毒性和独特的光学性质而备受关注。研究结果表明,以生物质材料为碳源的B-CDs通过结构设计和光功能化在众多应用领域展现出巨大潜力。然而,B-CDs的潜在机制和形成过程仍未得到充分阐明,系统总结仍需进一步完善。因此,本综述系统总结了B-CDs的合成方法、前驱体结构、形成机制、发光性质和主要应用,特别强调了其在传感、防伪、生物成像和光电子学方面的最新进展。此外,还阐明了在面向性能的可控制备和大规模生产中遇到的挑战。这一全面综述为B-CDs的进一步研究和多学科应用提供了理论基础,从而有助于推动大规模商业化和产业实施。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/98ff148ea944/nanomaterials-15-01279-g014a.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/0ea4fd2a8466/nanomaterials-15-01279-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/e148cb52ac10/nanomaterials-15-01279-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/f80099555d25/nanomaterials-15-01279-g009a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/60defbacbd15/nanomaterials-15-01279-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/a5ce85200a82/nanomaterials-15-01279-g011a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/8ef927e16a6b/nanomaterials-15-01279-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/704ab9d3d883/nanomaterials-15-01279-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/98ff148ea944/nanomaterials-15-01279-g014a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/0904d28ffd8d/nanomaterials-15-01279-g001a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/690308071c3c/nanomaterials-15-01279-g003a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/4dda7812850e/nanomaterials-15-01279-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/cbf8905ff5ef/nanomaterials-15-01279-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/bea2a33f9ea8/nanomaterials-15-01279-g005a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/a363fba1c09e/nanomaterials-15-01279-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/0ea4fd2a8466/nanomaterials-15-01279-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/e148cb52ac10/nanomaterials-15-01279-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/f80099555d25/nanomaterials-15-01279-g009a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/60defbacbd15/nanomaterials-15-01279-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/a5ce85200a82/nanomaterials-15-01279-g011a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/8ef927e16a6b/nanomaterials-15-01279-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/704ab9d3d883/nanomaterials-15-01279-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d1d/12389206/98ff148ea944/nanomaterials-15-01279-g014a.jpg

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本文引用的文献

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Hydrothermal Synthesis of Nitrogen-Doped Carbon Dots for Selective Fe Detection.用于选择性检测铁的氮掺杂碳点的水热合成
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Green Synthesis of Highly Fluorescent Carbon Dots from Groundnut Shell Biomass for Bioimaging Applications.
基于花生壳生物质的高荧光碳点的绿色合成及其在生物成像中的应用
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Sensitive Detection of Hg and l-Cysteine through Optical Asymmetry-Tuned Fluorescence Switch Off-On Behavior in N-Doped Chiral Carbon Dot.通过N掺杂手性碳点中光学不对称调谐荧光开关行为对汞和L-半胱氨酸进行灵敏检测。
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Nitrogen-doped carbon quantum dots as dual mode fluorescence sensors for the determination of food colorant quinoline yellow.氮掺杂碳量子点作为双模式荧光传感器用于食品着色剂喹啉黄的测定。
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