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多壁碳纳米管对普通硅酸盐水泥-硫铝酸盐水泥修补砂浆力学性能和微观结构的影响

Effects of Multi-Walled Carbon Nanotubes on Mechanical Properties and Microstructure of Ordinary Portland Cement-Sulfoaluminate Cement Repair Mortar.

作者信息

Zhou Qun, Cao Runzhuo, Ma Xiaodong

机构信息

College of Urban Construction, Xi'an Siyuan University, Xi'an 710038, China.

College of Materials Science and Engineering, Xi'an University of Architecture & Technology, Xi'an 710055, China.

出版信息

Materials (Basel). 2025 Aug 11;18(16):3748. doi: 10.3390/ma18163748.

Abstract

Multi-walled carbon nanotubes (MWCNTs) with high thermal conductivity and electrical conductivity are frequently considered as ideal nano-reinforced materials for the future. This paper investigated the potential application of MWCNTs in ordinary Portland cement-sulfoaluminate cement (OPC-SAC) repair mortar by analyzing mechanical and microstructural changes caused by MWCNTs. The test results revealed that MWCNTs greatly increased the strength of OPC-SAC binary repair mortar in the early days, and promoted sustained growth of long-term strength. The 10.39%/9.3 MPa increases in compressive strength can be attributed to 0.10 wt.% MWCNTs. MWCNTs promotes hydration of OPC-SAC composites through functional groups and nucleation effects, resulting in more C-S-H gels and AFt crystals. The X-ray computed tomography (X-CT), mercury intrusion porosimetry (MIP), and scanning electron microscope (SEM) results indicate that the nanofibers (MWCNTs) optimize the microstructure and microstructure of the composites. The nanofibers with high aspect ratio results enhance the crosslinking between hydration products, improve complexity (higher D) and integrity (more crosslinking sites), and reduce the formation and propagation of microcracks through bridging. The filling effect of nanoparticles refines the pore and reduces the pore volume, especially the volume of medium capillary pores. It is precisely these combined actions that improve the engineering performance of OPC-SAC binary repair mortar.

摘要

具有高导热性和导电性的多壁碳纳米管(MWCNTs)常被视为未来理想的纳米增强材料。本文通过分析MWCNTs引起的力学和微观结构变化,研究了MWCNTs在普通硅酸盐水泥-硫铝酸盐水泥(OPC-SAC)修补砂浆中的潜在应用。试验结果表明,MWCNTs在早期显著提高了OPC-SAC二元修补砂浆的强度,并促进了长期强度的持续增长。抗压强度提高10.39%/9.3MPa可归因于0.10wt.%的MWCNTs。MWCNTs通过官能团和成核作用促进OPC-SAC复合材料的水化,从而生成更多的C-S-H凝胶和AFt晶体。X射线计算机断层扫描(X-CT)、压汞法(MIP)和扫描电子显微镜(SEM)结果表明,纳米纤维(MWCNTs)优化了复合材料的微观结构。高长径比的纳米纤维增强了水化产物之间的交联,提高了复杂性(更高的D)和完整性(更多的交联位点),并通过桥接作用减少了微裂纹的形成和扩展。纳米颗粒的填充作用细化了孔隙并减小了孔隙体积,尤其是中等毛细孔隙的体积。正是这些综合作用提高了OPC-SAC二元修补砂浆的工程性能。

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