Yin Jinming, Kang Aihong, Kou Changjiang
Taizhou Institute of Science and Technology, Nanjing University of Science and Technology, Taizhou 225300, China.
College of Civil Engineering and Transportation, Yangzhou University, Yangzhou 225100, China.
Materials (Basel). 2025 Aug 15;18(16):3832. doi: 10.3390/ma18163832.
The poor quality of recycled coarse aggregate (RCA), particularly its high water absorption and low strength, has long restricted the development of recycled aggregate concrete (RAC). In this study, a novel combined spraying treatment method integrating cement slurry and a methyl sodium silicate (MSS) solution was proposed to improve the comprehensive performance of RCA. The effects of the treatment on RCA properties, including crushing value, water absorption, dynamic water absorption, apparent density, micromorphology, and contact angle, were systematically investigated. Furthermore, the treated RCA was incorporated into concrete to evaluate the mechanical strength, water absorption, and interfacial transition zone (ITZ) properties of the resulting RAC. The results indicated that cement slurry treatment alone significantly reduced the crushing value of the RCA by 30.1% but had little effect on water absorption. Conversely, MSS solution treatment reduced RCA water absorption by 29.6% without affecting its strength. The combined spraying method successfully enhanced both strength and water absorption performance. When applied in the RAC, cement slurry-treated RCA improved compressive and splitting tensile strengths, while MSS-treated RCA notably reduced water absorption. RAC prepared with combined-treated RCA achieved further strength improvement, and although its water absorption was not as low as that of MSS-only treated RAC, it still showed a substantial decrease compared to untreated RCA. Nanoindentation and microstructural analyses revealed that MSS enhanced the ITZ by forming a hydrophobic molecular film and reacting with new mortar, inhibiting water transport and improving RAC durability. An optimal MSS concentration of 10% was identified for achieving the best combined performance in strength and durability.
再生粗骨料(RCA)质量较差,尤其是其高吸水率和低强度,长期以来一直制约着再生骨料混凝土(RAC)的发展。在本研究中,提出了一种将水泥浆和甲基硅酸钠(MSS)溶液相结合的新型喷涂处理方法,以提高RCA的综合性能。系统研究了该处理对RCA性能的影响,包括压碎值、吸水率、动态吸水率、表观密度、微观形貌和接触角。此外,将处理后的RCA掺入混凝土中,以评估所得RAC的力学强度、吸水率和界面过渡区(ITZ)性能。结果表明,单独的水泥浆处理可使RCA的压碎值显著降低30.1%,但对吸水率影响不大。相反,MSS溶液处理使RCA的吸水率降低了29.6%,而不影响其强度。联合喷涂方法成功地提高了强度和吸水率性能。在RAC中应用时,水泥浆处理的RCA提高了抗压强度和劈裂抗拉强度,而MSS处理的RCA显著降低了吸水率。用联合处理的RCA制备的RAC强度进一步提高,虽然其吸水率不如仅用MSS处理的RAC低,但与未处理的RCA相比仍有大幅下降。纳米压痕和微观结构分析表明,MSS通过形成疏水分子膜并与新砂浆反应来增强ITZ,抑制水分传输并提高RAC的耐久性。确定了10%的最佳MSS浓度,以实现强度和耐久性方面的最佳综合性能。