文献检索文档翻译深度研究
Suppr Zotero 插件Zotero 插件
邀请有礼套餐&价格历史记录

新学期，新优惠

限时优惠:9月1日-9月22日

30天高级会员仅需29元

1天体验卡首发特惠仅需5.99元

了解详情
不再提醒
插件&应用
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
高级版
套餐订阅购买积分包
AI 工具
文献检索文档翻译深度研究
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2025

（金银）（苯硫酚丁酯）与（金银）（苯硫酚氟）：定制纳米团簇类似物的几何结构和光学性质

(AuAg)(SPh Bu) versus (AuAg)(SPhF): Tailoring the Geometric Structures and Optical Properties of Nanocluster Analogues.

作者信息

Han Jiaojiao, Li Hao, Shen Honglei, Xu Ying, Zou Xuejuan, Kang Xi, Zhu Manzhou

机构信息

Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Institutes of Physical Science and Information Technology and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China.

出版信息

Precis Chem. 2023 Mar 16;1(3):139-145. doi: 10.1021/prechem.2c00007. eCollection 2023 May 22.

DOI:10.1021/prechem.2c00007
PMID:40881502
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12382261/
Abstract

Monolayer-protected nanoclusters are ideal models for understanding the correlations between structures and properties of inorganic nanoparticles, especially for those molecules with identical sizes but comparable structures. Here, we controllably prepared and structurally determined a valence-neutral Au Ag (SPh Bu) (0 < < 4) nanocluster with comparable structure features to a well-known AuAg(SPhF) cluster. The Au Ag (SPh Bu) cluster contained a hollow Au@M metallic kernel (M = Au/Ag), 12 Au(SR) staples, and two bridging SR molecules, and its average molecular formula was determined to be AuAg(SPh Bu), as evidenced by X-ray crystallography and electrospray ionization mass spectrometry. Because of the ligand effect and the asymmetrical arrangement of the Au dopants in the dodecahedral cage, the Au Ag (SPh Bu) nanocluster exhibited lower molecular symmetry relative to AuAg(SPhF) in terms of the dodecahedral kernel and motif shell structures. Besides, the strong π-π interaction in Au Ag (SPh Bu) contributed to its enhanced photoluminescence intensity compared with AuAg(SPhF). The study, herein, extends the 44-metal-atom cluster family, thereby enabling us to better understand the correlations between their structures and properties at the atomic level.

摘要

单层保护的纳米团簇是理解无机纳米颗粒结构与性质之间相关性的理想模型，尤其适用于那些尺寸相同但结构可比的分子。在此，我们可控地制备并确定了一种价态中性的AuₓAg₄₋ₓ(SPhⁿBu)₄（0 < x < 4）纳米团簇的结构，其结构特征与著名的AuAg(SPhF)₄团簇相似。AuₓAg₄₋ₓ(SPhⁿBu)₄团簇包含一个中空的Au@M金属核（M = Au/Ag）、12个Au(SR)钉状物和两个桥连的SR分子，通过X射线晶体学和电喷雾电离质谱法确定其平均分子式为AuAg(SPhⁿBu)₄。由于配体效应以及十二面体笼中Au掺杂剂的不对称排列，就十二面体核和 motif 壳结构而言，AuₓAg₄₋ₓ(SPhⁿBu)₄纳米团簇相对于AuAg(SPhF)₄表现出较低的分子对称性。此外，AuₓAg₄₋ₓ(SPhⁿBu)₄中强烈的π-π相互作用导致其光致发光强度相对于AuAg(SPhF)₄有所增强。本文的研究扩展了44金属原子团簇家族，从而使我们能够在原子水平上更好地理解它们的结构与性质之间的相关性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/387f/12382261/0de1034c8c44/pc2c00007_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/387f/12382261/7159f192b0d5/pc2c00007_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/387f/12382261/6c58bbd83a44/pc2c00007_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/387f/12382261/1ccb23d5931e/pc2c00007_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/387f/12382261/0de1034c8c44/pc2c00007_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/387f/12382261/7159f192b0d5/pc2c00007_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/387f/12382261/6c58bbd83a44/pc2c00007_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/387f/12382261/1ccb23d5931e/pc2c00007_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/387f/12382261/0de1034c8c44/pc2c00007_0004.jpg

相似文献

[1]
(AuAg)(SPh Bu) versus (AuAg)(SPhF): Tailoring the Geometric Structures and Optical Properties of Nanocluster Analogues.

Precis Chem. 2023-3-16

[2]
Prescription of Controlled Substances: Benefits and Risks

2025-1

[3]
Does Augmenting Irradiated Autografts With Free Vascularized Fibula Graft in Patients With Bone Loss From a Malignant Tumor Achieve Union, Function, and Complication Rate Comparably to Patients Without Bone Loss and Augmentation When Reconstructing Intercalary Resections in the Lower Extremity?

Clin Orthop Relat Res. 2025-6-26

[4]
Does the Presence of Missing Data Affect the Performance of the SORG Machine-learning Algorithm for Patients With Spinal Metastasis? Development of an Internet Application Algorithm.

Clin Orthop Relat Res. 2024-1-1

[5]
Sertindole for schizophrenia.

Cochrane Database Syst Rev. 2005-7-20

[6]
The risks, benefits, and resource implications of different diets in gastrostomy-fed children: The YourTube mixed method study.

Health Technol Assess. 2025-7

[7]
The Black Book of Psychotropic Dosing and Monitoring.

Psychopharmacol Bull. 2024-7-8

[8]
Machine Learning-Guided Discovery of Alloy Nanoclusters: Steering Morphology-Based Activity and Selectivity Relationships in Bifunctional Electrocatalysts.

ACS Appl Mater Interfaces. 2025-7-16

[9]
Immunogenicity and seroefficacy of pneumococcal conjugate vaccines: a systematic review and network meta-analysis.

Health Technol Assess. 2024-7

[10]
Imidazolyl Phosphine as Versatile Hemilabile Ligand: Synthesis and Characterization of a New Tetracationic Au Nanocluster.

Chem Asian J. 2025-8

本文引用的文献

[1]
Achiral-Core-Metal Change in Isomorphic Enantiomeric AgAg and AuAg Clusters Triggers Circularly Polarized Phosphorescence.

J Am Chem Soc. 2022-11-2

[2]
Sulfide Boosting Near-Unity Photoluminescence Quantum Yield of Silver Nanocluster.

J Am Chem Soc. 2022-10-12

[3]
Ag Nanoclusters with Thermally Activated Delayed Fluorescence Protected by Ag/Cyanurate/Phosphine Metallamacrocyclic Monolayers through In-Situ Ligand Transesterification.

Angew Chem Int Ed Engl. 2022-11-7

[4]
An atomically precise silver nanocluster for artificial light-harvesting system through supramolecular functionalization.

Chem Sci. 2022-6-20

[5]
Single-Atom-Kernelled Nanocluster Catalyst.

Nano Lett. 2022-9-14

[6]
Revealing the composition-dependent structural evolution fundamentals of bimetallic nanoparticles through an inter-particle alloying reaction.

Chem Sci. 2022-3-25

[7]
Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au Nanocluster with Unique Prolate Shape.

J Am Chem Soc. 2022-2-9

[8]
Asymmetric Twisting of -Centered Octahedral Gold(I) Clusters by Chiral -Heterocyclic Carbene Ligation.

J Am Chem Soc. 2022-2-9

[9]
Full-Color Tunable Circularly Polarized Luminescence Induced by the Crystal Defect from the Co-assembly of Chiral Silver(I) Clusters and Dyes.

J Am Chem Soc. 2021-12-15

[10]
Toward Controlled Syntheses of Diphosphine-Protected Homochiral Gold Nanoclusters through Precursor Engineering.

ACS Nano. 2021-10-26

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

推荐工具

医学文档翻译智能文献检索