Kermanshahi Pouya Khattami, Refah Pooria, Akhbari Kamran
School of Chemistry, College of Science, University of Tehran Tehran Iran P.O. Box 14155-6455
RSC Adv. 2025 Aug 27;15(37):30654-30682. doi: 10.1039/d5ra04309c. eCollection 2025 Aug 22.
Through the gathering of metals and clusters with organic linkers, the metal-organic frameworks (MOFs) family emerges, representing highly applicable class of porous and crystalline materials in the world of chemistry. This class has the potential to shape the future of this field of science. The remarkable stability of zirconium and carboxylate ligands, coupled with the possibility of creating highly porous structures with a variety of arrangements, has led the authors to compile this review. In this study, we will investigate ten topologies that appeared in reported mesoporous Zr-Based MOFs and discuss their special properties. The applications of these structures are strongly influenced by their topologies, and the authors have concluded that understanding the topology and, more generally, the structure of MOFs helps to find the most optimal MOF for the intended application of researchers in each project.
通过将金属和簇与有机连接体聚集在一起，金属有机框架（MOF）家族应运而生，它代表了化学领域中一类极具应用价值的多孔晶体材料。这类材料有潜力塑造这一科学领域的未来。锆和羧酸盐配体的卓越稳定性，以及创造具有各种排列的高度多孔结构的可能性，促使作者撰写了这篇综述。在本研究中，我们将研究已报道的介孔锆基金属有机框架中出现的十种拓扑结构，并讨论它们的特殊性质。这些结构的应用受到其拓扑结构的强烈影响，作者得出结论，了解金属有机框架的拓扑结构，更广泛地说，了解其结构，有助于为每个项目中研究人员的预期应用找到最优化的金属有机框架。
