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魔芋葡甘露聚糖/刺槐豆胶稳定的丁香酚颗粒在魔芋葡甘露聚糖/壳聚糖薄膜中的性能及其在蓝莓保鲜中的应用

Performance of konjac glucomannan/tragacanth gum-stabilized eugenol particles in konjac glucomannan/chitosan films and their application in blueberry preservation.

作者信息

Li Meining, Wei Hanyu, Wang Xiang, Wang Yueguang, Lei Xin, Dai Oujun, Wen Chengrong, Pang Jie

机构信息

College of Food Science, Fujian Agriculture and Forestry University, Fuzhou 350002, China.

National Engineering Research Center of Seafood, School of Food Science and Technology, Dalian Polytechnic University, Dalian 116034, China.

出版信息

Carbohydr Polym. 2025 Nov 15;368(Pt 1):124117. doi: 10.1016/j.carbpol.2025.124117. Epub 2025 Jul 24.

Abstract

Environmentally friendly food packaging has emerged as a viable strategy to replace traditional plastic films. In this study, eugenol Pickering emulsion was constructed with konjac glucomannan (KGM) and tragacanth gum (GT) as stabilizers, and was introduced into the KGM/chitosan (CS) composite film by electrostatic action to develop a new type of active packaging film. Interfacial characterization revealed optimal emulsion stability at a 1:5 KGM-to-GT mass ratio. Compared to pure KGM and CS films, the KC-KT@EUG films maintained excellent flexibility while demonstrating superior WVP, OP, and UV barrier properties and soil degradability. FTIR and XRD confirmed successful component integration, TGA indicated reduced thermal stability, and SEM showed homogeneous emulsion dispersion in the film matrix. The KC-KT@EUG films exhibited remarkable antimicrobial and antioxidant activities, significantly outperforming PE films (p < 0.05) in decay rate, weight loss, firmness, and soluble solids of blueberries over 9 days of storage. Consequently, shelf life was extended by 10 days, demonstrating the films' great potential for fresh-produce preservation.

摘要

环境友好型食品包装已成为替代传统塑料薄膜的可行策略。在本研究中,以魔芋葡甘聚糖(KGM)和黄芪胶(GT)为稳定剂构建了丁香酚皮克林乳液,并通过静电作用将其引入KGM/壳聚糖(CS)复合膜中,以开发一种新型活性包装膜。界面表征显示,在KGM与GT质量比为1:5时乳液稳定性最佳。与纯KGM和CS膜相比,KC-KT@EUG膜保持了优异的柔韧性,同时展现出卓越的水蒸气透过率(WVP)、氧气透过率(OP)和紫外线阻隔性能以及土壤降解性。傅里叶变换红外光谱(FTIR)和X射线衍射(XRD)证实了各组分成功整合,热重分析(TGA)表明热稳定性降低,扫描电子显微镜(SEM)显示乳液在膜基质中分散均匀。KC-KT@EUG膜表现出显著的抗菌和抗氧化活性,在储存9天期间,蓝莓的腐烂率、失重、硬度和可溶性固形物方面显著优于聚乙烯(PE)膜(p < 0.05)。因此,货架期延长了10天,证明了该膜在新鲜农产品保鲜方面具有巨大潜力。

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