Wang Yueguang, Huang Zifeng, Zhang Di, Li Meining, Wen Xinyan, Lei Xin, Ye Ziwei, Pang Jie
College of Food Science, Fujian Agriculture and Forestry University, Fuzhou 350002, China.
College of Food Science, Fujian Agriculture and Forestry University, Fuzhou 350002, China.
Carbohydr Polym. 2025 Nov 15;368(Pt 2):124215. doi: 10.1016/j.carbpol.2025.124215. Epub 2025 Aug 14.
In this study, a novel multifunctional biosensor was developed based on the synergistic cross-linking of Konjac glucomannan (KGM) and κ-Carrageenan (KC). This biosensor exhibits high sensitivity for detecting triple signals: temperature, humidity, and strain. This matrix demonstrates excellent mechanical toughness (elongation at break >300 %) and a low Young's modulus (173.017 ± 1.51 kPa). This material exhibits a high thermal sensitivity of 1.67 %°C in temperature detection, and a linear response range of -15 % to 45 % was achieved within the temperature range of 4-40 °C. For humidity sensing, it provides a three-stage linear response with sensitivities of -89.75 %/% RH (0-40 % RH), -182.21 %/% RH (40-75 % RH), and -53.45 %/% RH (75-95 % RH). In terms of the strain sensing performance, this material demonstrates excellent wide-range detection capability (1-350 % strain), with a response value of approximately 875 %, and it also has high sensitivity (GF = 2.54 ± 0.06). Compared with traditional biomass-based gel sensors, the response limit of this sensor has been significantly increased while maintaining higher sensitivity. Experiments confirmed that the sensor can be monitored via resistance signals and exhibits stable performance (>2000 cycles) in flexible wearable applications such as human breathing monitoring and joint motion tracking, offering an innovative solution for intelligent medical monitoring and environmentally friendly electronic skin development.
在本研究中,基于魔芋葡甘聚糖(KGM)和κ-卡拉胶(KC)的协同交联开发了一种新型多功能生物传感器。该生物传感器在检测温度、湿度和应变这三种信号时表现出高灵敏度。这种基质具有出色的机械韧性(断裂伸长率>300%)和低杨氏模量(173.017±1.51kPa)。该材料在温度检测中表现出1.67%/°C的高热灵敏度,在4-40°C的温度范围内实现了-15%至45%的线性响应范围。对于湿度传感,它提供了一个三阶段线性响应,灵敏度分别为-89.75%/%RH(0-40%RH)、-182.21%/%RH(40-75%RH)和-53.45%/%RH(75-95%RH)。在应变传感性能方面,这种材料展示了出色的宽范围检测能力(1-350%应变),响应值约为875%,并且还具有高灵敏度(GF=2.54±0.06)。与传统的基于生物质的凝胶传感器相比,该传感器的响应极限在保持更高灵敏度的同时显著提高。实验证实,该传感器可以通过电阻信号进行监测,并且在诸如人体呼吸监测和关节运动跟踪等柔性可穿戴应用中表现出稳定的性能(>2000次循环),为智能医疗监测和环保型电子皮肤开发提供了一种创新解决方案。