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含碳化硅和氧化亚铁的微波敏感乳化沥青的电磁与流变性能研究

Research on Electromagnetic and Rheological Performance of Microwave-Sensitive Emulsified Asphalt Containing SiC and FeO.

作者信息

Wu Peng, Li Shuyin, Guo Haoyan, Zhang Haibao, He Rui

机构信息

Infrastructure Department, Chang'an University, Xi'an 710061, China.

School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China.

出版信息

Materials (Basel). 2025 Sep 12;18(18):4283. doi: 10.3390/ma18184283.

Abstract

The limited microwave-heating performance caused by moisture and ordinary aggregates limits the application efficiency of emulsified asphalt in rapid pavement repair engineering. Silicon carbide (SiC) and ferrosoferric oxide (FeO) were introduced as modifiers to prepare the microwave-sensitive emulsified asphalt used in this work. The electromagnetic properties, microwave heating properties, microstructural evolution law, and rheological performance of emulsified asphalt or its evaporation residue were studied. The results show that modification through SiC and FeO can produce a pronounced synergistic effect and can significantly enhance both the electromagnetic and high temperature rheological properties. Coupling polarization enhancement with magnetic responsiveness increases the dielectric constant and loss peaks compared with single doped samples. This compensates for the weak magnetic response or insufficient stiffness of single doped systems and leads to a maximum early-stage microwave heating rate increase of 176.2%. The rheological performance of the compound doped system is also markedly improved. The R (3.2 kPa) of the 2% SiC + 3% FeO group sample increased by 59.7% and the (3.2 kPa) decreased by 68.9% compared to the control group. The rigid and elastic complementarity of the two modifiers effectively suppresses irreversible deformation at high temperatures. Moreover, the modifiers accelerate the microstructural transition of the asphalt from a particulate state to a continuous phase under microwave exposure. Adjusting the compound doping ratio of SiC and FeO allows the system to be tailored for either high temperature stability or rapid heating, providing technical support for its application in microwave-assisted pavement repair field.

摘要

水分和普通集料导致的有限微波加热性能限制了乳化沥青在快速路面修复工程中的应用效率。本研究引入碳化硅(SiC)和四氧化三铁(Fe₃O₄)作为改性剂来制备微波敏感型乳化沥青。研究了乳化沥青及其蒸发残留物的电磁性能、微波加热性能、微观结构演变规律和流变性能。结果表明,通过SiC和Fe₃O₄改性可产生显著的协同效应,能显著提高电磁性能和高温流变性能。与单掺杂样品相比,耦合极化增强与磁响应性可增加介电常数和损耗峰。这弥补了单掺杂体系磁响应较弱或刚度不足的问题,使早期微波加热速率最大提高了176.2%。复合掺杂体系的流变性能也得到显著改善。与对照组相比,2%SiC + 3%Fe₃O₄组样品的R(3.2 kPa)增加了59.7%,δ(3.2 kPa)降低了68.9%。两种改性剂的刚性和弹性互补有效地抑制了高温下的不可逆变形。此外,改性剂在微波作用下加速了沥青从颗粒状态到连续相的微观结构转变。调整SiC和Fe₃O₄的复合掺杂比例可使体系针对高温稳定性或快速加热进行定制,为其在微波辅助路面修复领域的应用提供技术支持。

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