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橡胶聚氨酯凝胶混合料路用性能及破冰效果研究

Study on Road Performance and Ice-Breaking Effect of Rubber Polyurethane Gel Mixture.

作者信息

Chen Yuanzhao, Li Zhenxia, Guo Tengteng, Fang Chenze, Yang Jingyu, Guo Peng, Wang Chaohui, Bai Bing, Zhang Weiguang, Tang Deqing, Feng Jiajie

机构信息

School of Civil Engineering and Transportation, North China University of Water Resources and Electric Power, Zhengzhou 450045, China.

Henan Province Engineering Technology Research Center of Environment Friendly and High-Performance Pavement Materials, Zhengzhou 450045, China.

出版信息

Gels. 2025 Jun 29;11(7):505. doi: 10.3390/gels11070505.

Abstract

Aiming at the problems of serious pavement temperature diseases, low efficiency and high loss of ice-breaking methods, high occupancy rate of waste tires and the low utilization rate and insufficient durability of rubber particles, this paper aims to improve the service level of roads and ensure the safety of winter pavements. A pavement material with high efficiency, low carbon and environmental friendliness for active snow melting and ice breaking is developed. Firstly, NaOH, NaClO and KH550 were used to optimize the treatment of rubber particles. The hydrophilic properties, surface morphology and phase composition of rubber particles before and after optimization were studied, and the optimal treatment method of rubber particles was determined. Then, the optimized rubber particles were used to replace the natural aggregate in the polyurethane gel mixture by the volume substitution method, and the optimum polyurethane gel dosages and molding and curing processes were determined. Finally, the influence law of the road performance of RPGM was compared and analyzed by means of an indoor test, and the ice-breaking effect of RPGM was explored. The results showed that the contact angles of rubber particles treated with three solutions were reduced by 22.5%, 30.2% and 36.7%, respectively. The surface energy was improved, the element types on the surface of rubber particles were reduced and the surface impurities were effectively removed. Among them, the improvement effect of the KH550 solution was the most significant. With the increase in rubber particle content from 0% to 15%, the dynamic stability of the mixture gradually increases, with a maximum increase of 23.5%. The maximum bending strain increases with the increase in its content. The residual stability increases first and then decreases with the increase in rubber particle content, and the increase ranges are 1.4%, 3.3% and 0.5%, respectively. The anti-scattering performance increases with the increase in rubber content, and an excessive amount will lead to an increase in the scattering loss rate, but it can still be maintained below 5%. The fatigue life of polyurethane gel mixtures with 0%, 5%, 10% and 15% rubber particles is 2.9 times, 3.8 times, 4.3 times and 4.0 times higher than that of the AC-13 asphalt mixture, respectively, showing excellent anti-fatigue performance. The friction coefficient of the mixture increases with an increase in the rubber particle content, which can be increased by 22.3% compared with the ordinary asphalt mixture. RPGM shows better de-icing performance than traditional asphalt mixtures, and with an increase in rubber particle content, the ice-breaking ability is effectively improved. When the thickness of the ice layer exceeds 9 mm, the ice-breaking ability of the mixture is significantly weakened. Mainly through the synergistic effect of stress coupling, thermal effect and interface failure, the bonding performance of the ice-pavement interface is weakened under the action of driving load cycle, and the ice layer is loosened, broken and peeled off, achieving efficient de-icing.

摘要

针对路面温度病害严重、破冰方法效率低且损耗高、废旧轮胎占有率高以及橡胶颗粒利用率低和耐久性不足等问题,本文旨在提高道路服务水平并确保冬季路面安全。研发了一种高效、低碳、环保的主动融雪破冰路面材料。首先,采用NaOH、NaClO和KH550对橡胶颗粒进行优化处理。研究了优化前后橡胶颗粒的亲水性、表面形貌和相组成,确定了橡胶颗粒的最佳处理方法。然后,采用体积置换法用优化后的橡胶颗粒替代聚氨酯凝胶混合料中的天然集料,确定了最佳聚氨酯凝胶用量及成型和养护工艺。最后,通过室内试验对比分析了橡胶颗粒聚氨酯凝胶混合料(RPGM)路用性能的影响规律,探究了RPGM的破冰效果。结果表明,三种溶液处理后的橡胶颗粒接触角分别降低了22.5%、30.2%和36.7%。表面能得到提高,橡胶颗粒表面的元素种类减少,表面杂质被有效去除。其中,KH550溶液的改善效果最为显著。随着橡胶颗粒含量从0%增加到15%,混合料的动稳定度逐渐增大,最大增幅为23.5%。最大弯拉应变随其含量的增加而增大。残留稳定度随橡胶颗粒含量的增加先增大后减小,增幅分别为1.4%、3.3%和0.5%。抗飞散性能随橡胶含量的增加而提高,过量会导致飞散损失率增大,但仍可保持在5%以下。橡胶颗粒含量为0%、5%、10%和15%的聚氨酯凝胶混合料的疲劳寿命分别比AC-13沥青混合料高2.9倍、3.8倍、4.3倍和4.0倍,表现出优异的抗疲劳性能。混合料的摩擦系数随橡胶颗粒含量的增加而增大,相比普通沥青混合料可提高22.3%。RPGM比传统沥青混合料表现出更好的除冰性能,随着橡胶颗粒含量的增加,破冰能力有效提高。当冰层厚度超过9mm时,混合料的破冰能力显著减弱。主要通过应力耦合、热效应和界面破坏的协同作用,在行车荷载循环作用下削弱冰-路面界面的粘结性能,使冰层松动、破碎和剥落,实现高效除冰。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4293/12294624/fded6b20a09e/gels-11-00505-g001.jpg

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