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用于监测核工业中有毒元素的荧光探针:综述

Fluorescent Probes for Monitoring Toxic Elements from the Nuclear Industry: A Review.

作者信息

Poulin-Ponnelle Clovis, Boudreau Denis, Larivière Dominic

机构信息

Radioecology Laboratory, Chemistry Department, Laval University, 1045 Avenue de la Médecine, Québec, QC G1V 0A6, Canada.

出版信息

Sensors (Basel). 2025 Sep 18;25(18):5835. doi: 10.3390/s25185835.

DOI:10.3390/s25185835
PMID:41013075
Abstract

With nuclear power playing an increasing role in efforts to reduce carbon emissions, the development of effective and sensitive monitoring tools for (radio)toxic elements in the environment has become essential. This review highlights recent advances in fluorescent probes developed for the detection of key elements associated with the nuclear industry, including uranium, cesium, strontium, technetium, zirconium, and beryllium. Various sensor platforms, ranging from organic ligands and DNAzymes to metal-organic frameworks and quantum dots, offer promising features, such as high sensitivity, selectivity, and suitability for environmental matrices. Several recent designs now achieve detection limits in the nanomolar to picomolar range, revealing new perspectives for environmental and biological applications.

摘要

随着核能在减少碳排放的努力中发挥越来越重要的作用,开发用于监测环境中(放射性)有毒元素的有效且灵敏的工具变得至关重要。本综述重点介绍了用于检测与核工业相关的关键元素(包括铀、铯、锶、锝、锆和铍)的荧光探针的最新进展。从有机配体、脱氧核酶到金属有机框架和量子点等各种传感器平台都具有诸如高灵敏度、选择性以及适用于环境基质等有前景的特性。最近的一些设计现已实现纳摩尔至皮摩尔范围内的检测限,为环境和生物应用揭示了新的前景。

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本文引用的文献

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Advancing environmental safety and public health: a comprehensive review of luminescent probes for radioactive element detection.推进环境安全与公众健康:放射性元素检测发光探针的综合综述
Analyst. 2025 Sep 22;150(19):4252-4268. doi: 10.1039/d5an00683j.
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Highly selective and portable fluorescent detection of uranyl in groundwater via AIEgen-labeled protein cleavage.
Spectrochim Acta A Mol Biomol Spectrosc. 2026 Jan 5;344(Pt 1):126685. doi: 10.1016/j.saa.2025.126685. Epub 2025 Jul 10.
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A Luminescent Sensor for Trace Uranyl in Nature Water Systems Using a Terbium(III)-Organic Framework.
Inorg Chem. 2025 Jul 28;64(29):14741-14746. doi: 10.1021/acs.inorgchem.5c01966. Epub 2025 Jul 15.
4
Detection of radioactive ions: current status of nanomaterial-based sensors.放射性离子的检测:基于纳米材料的传感器的现状
Mikrochim Acta. 2025 Jun 30;192(7):465. doi: 10.1007/s00604-025-07308-5.
5
Highly Sensitive and Selective Detection of Uranyl Ions Based on a Tb-Functionalized MOF via Competitive Host-Guest Coordination.基于Tb功能化金属有机框架通过竞争性主客体配位对铀酰离子进行高灵敏度和高选择性检测
Inorg Chem. 2025 Feb 24;64(7):3616-3625. doi: 10.1021/acs.inorgchem.4c05586. Epub 2025 Feb 11.
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Detection of uranyl ions by single-hairpin based self-hybridization chain reaction.
Talanta. 2025 Apr 1;285:127374. doi: 10.1016/j.talanta.2024.127374. Epub 2024 Dec 13.
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Highly sensitive and specific uranyl ion detection by a fluorescent sensor containing uranyl-specific recognition sites.通过含有铀酰特异性识别位点的荧光传感器进行高灵敏度和高特异性的铀酰离子检测。
Sci Bull (Beijing). 2025 Jan 15;70(1):70-77. doi: 10.1016/j.scib.2024.08.013. Epub 2024 Aug 16.
8
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