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国际抗癌联盟(U.I.C.C.)罗德西亚温石棉和青石棉在水溶液中的吸附特性——阳离子耗竭的影响

Adsorption properties of U.I.C.C. Rhodesian chrysotile and crocidolite in aqueous solution -- effects of cation depletion.

作者信息

Valerio F, Puntoni R, Santi L

出版信息

Am Ind Hyg Assoc J. 1979 Sep;40(9):781-8. doi: 10.1080/15298667991430299.

Abstract

Adsorption properties of U.I.C.C. Rhodesian chrysotile and crocidolite were tested in aqueous solution with acid and basic dyes (Eosine Y. Picric Acid, Acridine Orange and Methylene Blue). Rates of adsorption showed a diffusion of only basic dyes in micropores of fibers. The strong adsorption of basic dyes on the surface of the fibers led us to suppose that the active sites have a negative charge. Our hypothesis was supported by the verification of an increase in adsorption capacity whick depends on depletion of Mg++ from chrysotile and of Fe+++ from crocidolite.

摘要

在水溶液中,使用酸性和碱性染料(伊红Y、苦味酸、吖啶橙和亚甲基蓝)对国际抗癌联盟(U.I.C.C.)的罗德西亚温石棉和青石棉的吸附特性进行了测试。吸附速率表明只有碱性染料在纤维微孔中扩散。碱性染料在纤维表面的强烈吸附使我们推测活性位点带负电荷。通过验证吸附容量的增加得到了我们假设的支持,吸附容量的增加取决于温石棉中Mg++的消耗和青石棉中Fe+++的消耗。

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