胆红素在非质子溶剂中的金属配合物。
Metal complexes of bilirubin in aprotic solvents.
作者信息
Hutchinson D W, Johnson B, Knell A J
出版信息
Biochem J. 1973 Jun;133(2):399-400. doi: 10.1042/bj1330399.
Abstract
Bilirubin reacts with zinc acetate, cadmium acetate or cobaltous acetate in dry dipolar aprotic solvents to form highly coloured complexes. The complex formed in NN-dimethylformamide can be isolated as a solid with bilirubin:zinc:acetate:NN-dimethylformamide molar proportions of 1:3:2:2. Water will decompose these complexes, with the regeneration of bilirubin.
摘要
胆红素在干燥的偶极非质子溶剂中与醋酸锌、醋酸镉或醋酸钴反应，形成颜色很深的络合物。在N，N -二甲基甲酰胺中形成的络合物可以以胆红素：锌：醋酸根：N，N -二甲基甲酰胺摩尔比为1:3:2:2的固体形式分离出来。水会使这些络合物分解，胆红素再生。
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