Downey W K, Flynn M P, Aherne S A
J Dairy Res. 1975 Feb;42(1):21-9. doi: 10.1017/s0022029900015077.
Milks (bovine and human) and dairy products (butter, cheese, skim and whey powders, calf-replacer, casein, butter-oil and dietetic food) were collected during 1971/2 throughout Ireland together with a more limited samples of the 10 major animal feed ingredients, and analysed for organochlorine insecticide residues using electron-capture gas chromatography. The different materials contained low or negligible levels of chlorinated insecticides. Apart from some of the animal feed ingredients the DDT residues were generally the predominant contaminants detected together with lower levels of gamma-BHC (lindane), aldrin/dieldrin and heptachlor/heptachlor epoxide. The maximum levels of these insecticides in the bovine milk and dairy products (511, 100, 62 and 21 mug/kg fat respectively) constitute only 50% or less of the Codex Tolerance Limits. The correspondingly low residue levels in the human milk (maxima of 128, 1, 1, and 5 mug/kg fat respectively) which at most represent insecticidal ingestion by infants equivalent to 13, 0-05, 5 and 5% respectively of the WHO/FAO acceptable daily intake for DDE, gamma-BHC, aldrin/dieldrin and heptachlor/heptachlor epoxide again pose no obvious health hazards and are strongly indicative of negligible organochlorine contamination in the general diet. The samples of animal feed ingredients examined also contained trace levels of ogranochlorines (maxima of 0-9, 0-1, 1-6 and 1-0 mug/kg respectively). More extensive monitoring of the residues in animal feed ingredients (the most probable source of milk contamination is advocated, and the desirability of tolerance limits for insecticides in animal feeds discussed.
1971年至1972年期间,在爱尔兰各地收集了牛奶(牛乳与人乳)和乳制品(黄油、奶酪、脱脂奶粉、乳清粉、犊牛代乳料、酪蛋白、黄油油和营养食品),同时还收集了数量有限的10种主要动物饲料成分样本,并采用电子捕获气相色谱法分析了其中的有机氯杀虫剂残留量。不同材料中含有的氯化杀虫剂含量较低或可忽略不计。除了一些动物饲料成分外,滴滴涕残留通常是检测到的主要污染物,同时还含有较低水平的γ-六六六(林丹)、艾氏剂/狄氏剂和七氯/七氯环氧化物。这些杀虫剂在牛乳和乳制品中的最高含量(分别为511、100、62和21微克/千克脂肪)仅占食品法典委员会规定的耐受限量的50%或更低。人乳中相应的低残留水平(分别最高为128、1、1和5微克/千克脂肪),最多相当于婴儿摄入的杀虫剂量分别占世界卫生组织/联合国粮农组织规定的滴滴涕、γ-六六六、艾氏剂/狄氏剂和七氯/七氯环氧化物每日可接受摄入量的13%、0.05%、5%和5%,同样不会对健康造成明显危害,有力地表明一般饮食中的有机氯污染可忽略不计。所检测的动物饲料成分样本中也含有痕量的有机氯(分别最高为0.9、0.1、1.6和1.0微克/千克)。有人主张对动物饲料成分中的残留进行更广泛的监测(这是牛奶污染最可能的来源),并讨论了对动物饲料中杀虫剂设定耐受限量的必要性。