Copolymerization of 1,6-anhydro-2,3,4-tri-O-(p-methylbenzyl)-beta-D-glucopyranose and 1,6-anhydro-2,3,4-tri-O-benzyl-beta-D-galactopyranose. Possible application to the synthesis of stereoregular heteropolysaccharides and oligosaccharides.
作者信息
Lin J W, Schuerch C
出版信息
Macromolecules. 1973 May-Jun;6(3):320-4. doi: 10.1021/ma60033a003.
PMID:4778415
Abstract
摘要
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1
Copolymerization of 1,6-anhydro-2,3,4-tri-O-(p-methylbenzyl)-beta-D-glucopyranose and 1,6-anhydro-2,3,4-tri-O-benzyl-beta-D-galactopyranose. Possible application to the synthesis of stereoregular heteropolysaccharides and oligosaccharides.1,6-脱水-2,3,4-三-O-(对甲基苄基)-β-D-吡喃葡萄糖与1,6-脱水-2,3,4-三-O-苄基-β-D-吡喃半乳糖的共聚反应。在立体规整杂多糖和寡糖合成中的可能应用。
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Synthesis of heparin fragments. A chemical synthesis of the pentasaccharide O-(2-deoxy-2-sulfamido-6-O-sulfo-alpha-D-glucopyranosyl)-(1-4 )-O-(beta-D-glucopyranosyluronic acid)-(1-4)-O-(2-deoxy-2-sulfamido-3,6-di-O-sulfo-alpha-D-glu copyranosyl)-(1-4)-O-(2-O-sulfo-alpha-L-idopyranosyluronic acid)-(1-4)-2-deoxy-2-sulfamido-6-O-sulfo-D-glucopyranose decasodium salt, a heparin fragment having high affinity for antithrombin III.肝素片段的合成。五糖O-（2-脱氧-2-磺酰胺基-6-O-磺基-α-D-吡喃葡萄糖基）-（1→4）-O-（β-D-吡喃葡萄糖醛酸）-（1→4）-O-（2-脱氧-2-磺酰胺基-3,6-二-O-磺基-α-D-吡喃葡萄糖基）-（1→4）-O-（2-O-磺基-α-L-吡喃艾杜糖醛酸）-（1→4）-2-脱氧-2-磺酰胺基-6-O-磺基-D-吡喃葡萄糖十钠盐的化学合成，一种对抗凝血酶III具有高亲和力的肝素片段。
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