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在施用2,4,5-三氯苯氧基乙酸酯后叶片中的氯代苯氧基乙酸衍生物和四氯二苯并对二恶英

Chlorinated phenoxyacetic acid derivatives and tetrachlorodibenzo-p-dioxin in foliage after application of 2,4,5-trichlorophenoxyacetic acid esters.

作者信息

Sundström G, Jensen S, Jansson B, Erne K

出版信息

Arch Environ Contam Toxicol. 1979;8(4):441-8. doi: 10.1007/BF01056350.

DOI:10.1007/BF01056350
PMID:485212
Abstract

Six reforestation areas were sprayed with 2,4,5-T esters. Leaf samples from the areas were analyzed for the esters, tetrachlorodioxin, and dehalogenated phenoxyacetic acid esters. Tetrachlorodioxin was found in one leaf sample only, but the level found, relative to the amount of 2,4,5-T ester found, was lower than in the formulation material used in the study. The concentration of the dichlorophenoxyacetic acid esters present in several leaf samples was greater, relative to the 2,4,5-T ester, which indicated a photochemical breakdown of the 2,4,5-T in the environment.

摘要

六个重新造林区域喷洒了2,4,5-T酯。对这些区域的树叶样本进行了酯类、四氯二恶英和脱卤苯氧基乙酸酯的分析。仅在一个树叶样本中发现了四氯二恶英,但相对于所发现的2,4,5-T酯的量而言,所发现的该物质水平低于研究中使用的配方材料中的水平。相对于2,4,5-T酯,几个树叶样本中存在的二氯苯氧基乙酸酯浓度更高,这表明环境中2,4,5-T发生了光化学分解。

相似文献

1
Chlorinated phenoxyacetic acid derivatives and tetrachlorodibenzo-p-dioxin in foliage after application of 2,4,5-trichlorophenoxyacetic acid esters.在施用2,4,5-三氯苯氧基乙酸酯后叶片中的氯代苯氧基乙酸衍生物和四氯二苯并对二恶英
Arch Environ Contam Toxicol. 1979;8(4):441-8. doi: 10.1007/BF01056350.
2
[Determination of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in 2,4,5-trichlorophenoxyacetic acid, 2,4,5-trichlorophenoxyacetic acid-alkylesters and in the corresponding herbicide formulations (author's transl)].2,4,5-三氯苯氧乙酸、2,4,5-三氯苯氧乙酸烷基酯及相应除草剂制剂中2,3,7,8-四氯二苯并-对-二噁英(TCDD)的测定(作者译)
Z Lebensm Unters Forsch. 1979 Jan 29;168(1):21-4. doi: 10.1007/BF01267755.
3
A search for 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in an environment exposed annually to 2,4,5-trichlorophenoxyacetic acid ester (2,4,5-T) herbicides.在每年接触2,4,5-三氯苯氧乙酸酯(2,4,5-T)除草剂的环境中对2,3,7,8-四氯二苯并对二恶英(TCDD)进行搜索。
Bull Environ Contam Toxicol. 1977 Oct;18(4):478-85. doi: 10.1007/BF01683720.
4
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J Assoc Off Anal Chem. 1985 Sep-Oct;68(5):917-21.
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Bull Environ Contam Toxicol. 1977 Aug;18(2):123-30. doi: 10.1007/BF01686318.
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Analysis of some older Scandinavian formulations of 2,4-dichlorophenoxy acetic acid and 2,4,5-trichlorophenoxy acetic acid for contents of chlorinated dibenzo-p-dioxins and dibenzofurans.
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Automated cleanup of herbicides by adsorption chromatography for the determination of 2,3,7,8-tetrachlorodibenzo-p-dioxin.通过吸附色谱法自动净化除草剂以测定2,3,7,8-四氯二苯并对二恶英。
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The determination of 2,3,7,8-tetrachlorodibenzo-p-dioxin in biological extracts by gas chromatography mass spectrometry.采用气相色谱-质谱联用技术测定生物提取物中的2,3,7,8-四氯二苯并对二噁英。
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Determination of 2,3,7,8-tetrachlorodibenzo-1,4-dioxin at parts per billion levels in technical-grade 2,4,5-trichlorophenoxyacetic acid, in 2,4,5-T alkyl ester and 2,4,5-T amine salt herbicide formulations by quadrupole mass fragmentography.采用四极质谱碎片分析法测定工业级2,4,5-三氯苯氧乙酸、2,4,5-T烷基酯和2,4,5-T胺盐除草剂制剂中十亿分之一水平的2,3,7,8-四氯二苯并-1,4-二噁英。
J Chromatogr. 1974 Mar 13;90(1):71-7. doi: 10.1016/s0021-9673(01)94775-2.
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Accidental release of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) at Sèveso, Italy.
Ecotoxicol Environ Saf. 1980 Sep;4(3):283-97. doi: 10.1016/0147-6513(80)90031-7.

本文引用的文献

1
Photodecomposition of Chlorinated Dibenzo-p-Dioxins.光降解氯代二苯并对二恶英。
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Riboflavin photosensitized oxidation of 2,4-dichlorophenol: assessment of possible chlorinated dioxin formation.
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3
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A search for 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in an environment exposed annually to 2,4,5-trichlorophenoxyacetic acid ester (2,4,5-T) herbicides.在每年接触2,4,5-三氯苯氧乙酸酯(2,4,5-T)除草剂的环境中对2,3,7,8-四氯二苯并对二恶英(TCDD)进行搜索。
Bull Environ Contam Toxicol. 1977 Oct;18(4):478-85. doi: 10.1007/BF01683720.
7
Persistence of 2,4-D,2,4,5-T and dicamba in a dykeland soil.
Bull Environ Contam Toxicol. 1977 Aug;18(2):210-8. doi: 10.1007/BF01686069.
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Environmental degradation of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD).2,3,7,8-四氯二苯并对二恶英(TCDD)的环境降解
Science. 1977 Mar 25;195(4284):1337-8. doi: 10.1126/science.841331.
9
Persistence of 2,4-D and 2,4,5-T in chaparral soil and vegetation.
Bull Environ Contam Toxicol. 1977 Jan;17(1):1-8. doi: 10.1007/BF01685256.
10
Synthesis of [2,3,7,8-37C1]tetrachloro[1,4,6,9-2H]dibenzo-p-dioxin and its use as an internal standard in quantitations of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) by mass fragmentography.[2,3,7,8-37C1]四氯[1,4,6,9-2H]二苯并-对-二噁英的合成及其作为内标物在通过质量碎片分析法对2,3,7,8-四氯二苯并-对-二噁英(TCDD)进行定量分析中的应用。
Acta Pharm Suec. 1978;15(5):321-6.