Concurrent general acid-electrostatic catalysis in vinyl ether hydrolysis and aspartic-52 of lysozyme. - Suppr | 超能文献

Concurrent general acid-electrostatic catalysis in vinyl ether hydrolysis and aspartic-52 of lysozyme.

作者信息

Loudon G M, Smith C K, Zimmerman S E

出版信息

J Am Chem Soc. 1974 Jan 23;96(2):465-79. doi: 10.1021/ja00809a024.

DOI:10.1021/ja00809a024

Abstract

摘要

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Concurrent general acid-electrostatic catalysis in vinyl ether hydrolysis and aspartic-52 of lysozyme.

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Separation of factors responsible for lysozyme catalysis.

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Ionization behavior of the catalytic carboxyls of lysozyme. Effects of temperature.

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Ionization behavior of the catalytic carboxyls of lysozyme. Effects of ionic strength.溶菌酶催化性羧基的电离行为。离子强度的影响。

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Interpretation of protein titration curves. Application to lysozyme.蛋白质滴定曲线的解读。应用于溶菌酶。

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Reexamination of the role of Asp20 in catalysis by bacteriophage T4 lysozyme.噬菌体T4溶菌酶中Asp20在催化作用中的角色再探讨。

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Electrostatic free energy of lysozyme.溶菌酶的静电自由能。

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