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理想自缔合体系的维里展开式。

Virial expansions for ideal self-associating systems.

作者信息

Stafford W F, Yphantis D A

出版信息

Biophys J. 1972 Oct;12(10):1359-65. doi: 10.1016/S0006-3495(72)86167-8.

Abstract

Theoretical virial equations for self-associating systems governed by mass action have been derived assuming the solute to be ideal except for this solutesolute interaction. In particular, monomer-polymer association involving two molecular species and isodesmic association involving an indefinite number of molecular species have been treated analytically. The usefulness of such virial equations is severely limited by their extremely narrow interval of convergence.

摘要

对于由质量作用控制的自缔合系统,已推导了理论维里方程,其中假设除溶质 - 溶质相互作用外溶质是理想的。特别地,对涉及两种分子物种的单体 - 聚合物缔合以及涉及不确定数量分子物种的等键缔合进行了分析处理。这类维里方程的实用性受到其极窄收敛区间的严重限制。

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本文引用的文献

1
Sedimentation equilibrium of low-molecular-weight associating solutes.
Ann N Y Acad Sci. 1969 Nov 7;164(1):279-93. doi: 10.1111/j.1749-6632.1969.tb14044.x.
2
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