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发现一系列新的带有邻位二甲基支链的长链二元羧酸是丁酸弧菌属脂质的主要成分。

A new series of long-chain dicarboxylic acids with vicinal dimethyl branching found as major components of the lipids of Butyrivibrio spp.

作者信息

Klein R A, Hazlewood G P, Kemp P, Dawson R M

出版信息

Biochem J. 1979 Dec 1;183(3):691-700. doi: 10.1042/bj1830691.

Abstract
  1. Some members of the genus Butyrivibrio, including a general fatty acid auxotroph (strain S2), contain as a major part of their complex lipids a high-molecular-weight component that is probably formed by the union of two fatty acid chains [Hazlewood & Dawson (1979) J. Gen. Microbiol. 112, 15--27]. 2. Proton and 13C n.m.r. and i.r. and mass spectroscopy were used to examine a homologous series of these moieties and, in addition, the hydrocarbon derivative of one homologue and several synthetic compounds. 3. The results indicate that the high-molecular-weight components are a series of long-chain dicarboxylic acids containing vicinal dimethyl branching, located near the centre of the chain.
摘要
  1. 丁酸弧菌属的一些成员,包括一种普通脂肪酸营养缺陷型菌株(菌株S2),其复合脂质的主要部分含有一种高分子量成分,该成分可能由两条脂肪酸链结合而成[黑兹尔伍德和道森(1979年)《普通微生物学杂志》112卷,第15 - 27页]。2. 利用质子和碳-13核磁共振、红外光谱和质谱对这些部分的同系物系列进行了研究,此外还研究了一种同系物的烃衍生物和几种合成化合物。3. 结果表明,高分子量成分是一系列含有邻位二甲基支链的长链二元羧酸,支链位于链的中心附近。
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bef8/1161651/d43f13b58fb7/biochemj00451-0217-a.jpg

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