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滴滴涕:参与紫外线可检测的电荷转移络合作用。

DDT: participation in ultraviolet-detectable, charge-transfer complexation.

作者信息

Wilson W E, Fishbein L, Clements S T

出版信息

Science. 1971 Jan 15;171(3967):180-2. doi: 10.1126/science.171.3967.180.

DOI:10.1126/science.171.3967.180
PMID:5538828
Abstract

The chlorophenyl groups of DDT and several of its metabolites are capable of participating in a charge-transfer interaction with tetracyanoethylene detectable in the ultraviolet region of the spectrum. In addition, during a change of state DDT undergoes ultraviolet spectral alterations that closely resemble those previously claimed to support the hypothesis suggesting charge-transfer interaction between this pesticide and a component of insect nerve tissue. The pesticide DDT possesses structural characteristics that would permit it to participate in several types of molecular association.

摘要

滴滴涕及其几种代谢产物的氯苯基能够与四氰基乙烯发生电荷转移相互作用,这在光谱的紫外区域可以检测到。此外,在状态变化过程中,滴滴涕会发生紫外光谱变化,这与先前声称支持该杀虫剂与昆虫神经组织成分之间存在电荷转移相互作用这一假设的变化非常相似。杀虫剂滴滴涕具有使其能够参与几种分子缔合类型的结构特征。

相似文献

1
DDT: participation in ultraviolet-detectable, charge-transfer complexation.滴滴涕:参与紫外线可检测的电荷转移络合作用。
Science. 1971 Jan 15;171(3967):180-2. doi: 10.1126/science.171.3967.180.
2
Infrared studies of DDT, structurally related halogenated pesticides, and some metabolites.滴滴涕、结构相关卤代农药及某些代谢物的红外光谱研究。
J Assoc Off Anal Chem. 1972 Jan;55(1):15-31.
3
Induced photolysis of DDT.滴滴涕的诱导光解作用。
Science. 1970 Jul 24;169(3943):368-70. doi: 10.1126/science.169.3943.368.
4
[COMPLEXES BY CHARGE TRANSFER BETWEEN MUTAGENIC AGENTS AND TETRACYANOETHYLENE].[诱变剂与四氰基乙烯之间电荷转移形成的配合物]
C R Hebd Seances Acad Sci. 1965 Mar 29;260:3775-6.
5
Photochemical decompsosition of DDT by a free-radical mechanism.滴滴涕通过自由基机制进行的光化学分解
Science. 1969 May 30;164(3883):1083-5. doi: 10.1126/science.164.3883.1083.
6
Effects of feeding activated carbon on growth rate and pesticide concentrations in adipose tissues of steers fed apple waste.给饲喂苹果废料的阉牛投喂活性炭对其生长速率及脂肪组织中农药浓度的影响。
J Anim Sci. 1971 Dec;33(6):1361-4. doi: 10.2527/jas1971.3361361x.
7
Dechlorination of DDT in frozen blood.冷冻血液中滴滴涕的脱氯作用。
Science. 1967 May 5;156(3775):663-5. doi: 10.1126/science.156.3775.663.
8
Comparative excretion and retention of DDT analogs by dairy cows.奶牛对滴滴涕类似物的排泄与潴留比较
J Dairy Sci. 1969 Nov;52(11):1800-5. doi: 10.3168/jds.S0022-0302(69)86844-X.
9
Anaerobic biodegradation of DDT to DDD in soil.土壤中滴滴涕厌氧生物降解为滴滴滴
Science. 1967 May 26;156(3778):1116-7. doi: 10.1126/science.156.3778.1116.
10
Regulation of succinate dehydrogenase activity by reduced coenzymes Q10.还原型辅酶Q10对琥珀酸脱氢酶活性的调节
Biochemistry. 1971 Jul 6;10(14):2726-33. doi: 10.1021/bi00790a011.

引用本文的文献

1
Ficoll density gradient separation of extracellular DDT from Chlorella.从小球藻中通过Ficoll密度梯度分离细胞外滴滴涕
Bull Environ Contam Toxicol. 1974 Nov;12(5):562-6. doi: 10.1007/BF01684919.