• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

Solution photochemistry of thymine and uracil.

作者信息

Lamola A A, Mittal J P

出版信息

Science. 1966 Dec 23;154(3756):1560-1. doi: 10.1126/science.154.3756.1560.

DOI:10.1126/science.154.3756.1560
PMID:5924924
Abstract

With dienes as specific triplet quenchers, it has been shown that the photodimerization of thymine in acetonitrile proceeds entirely through the triplet state and the photodimerization of uracil in acetonitrile or in water proceeds in part through the triplet state. The photohydration of uracil probably does not involve the triplet state. Efficiencies of intersystem crossing of thymine and uracil in acetonitrile were determined.

摘要

相似文献

1
Solution photochemistry of thymine and uracil.
Science. 1966 Dec 23;154(3756):1560-1. doi: 10.1126/science.154.3756.1560.
2
Studies on thymine and uracil triplet excited state in acetonitrile and water.乙腈和水中胸腺嘧啶与尿嘧啶三重激发态的研究。
Photochem Photobiol. 1975 Dec;22(6):231-5. doi: 10.1111/j.1751-1097.1975.tb06741.x.
3
Photodimerization of pyrimidine nucleic acid derivatives in aqueous solution and the effect of oxygen.嘧啶核酸衍生物在水溶液中的光二聚作用及氧的影响。
Biochem Biophys Res Commun. 1967 May 25;27(4):431-6. doi: 10.1016/s0006-291x(67)80002-0.
4
Tautomerism of uracil and thymine in aqueous solution: spectroscopic evidence.尿嘧啶和胸腺嘧啶在水溶液中的互变异构:光谱学证据。
Proc Natl Acad Sci U S A. 1972 Sep;69(9):2488-91. doi: 10.1073/pnas.69.9.2488.
5
Transients of uracil and thymine derivatives and the quantum yields of electron ejection and intersystem crossing upon 20 ns photolysis at 248 nm.
Photochem Photobiol. 1990 Nov;52(5):935-48. doi: 10.1111/j.1751-1097.1990.tb01810.x.
6
Photochemistry of 2,4-diketopyrimidines. Photodimerization, photohydration and stacking association of 1,3-dimethyluracil in aqueous solution.2,4-二酮嘧啶的光化学。1,3-二甲基尿嘧啶在水溶液中的光二聚化、光水合作用和堆积缔合。
Acta Biochim Pol. 1973;20(3):313-24.
7
Even-odd alternation in mass spectrum of thymine and uracil clusters: evidence of intracluster photodimerization.胸腺嘧啶和尿嘧啶团簇质谱中的奇偶交替:团簇内光二聚化的证据。
Proc Natl Acad Sci U S A. 2001 Apr 24;98(9):4841-3. doi: 10.1073/pnas.091094998. Epub 2001 Apr 10.
8
Direct Observation of Triplet-State Population Dynamics in the RNA Uracil Derivative 1-Cyclohexyluracil.RNA尿嘧啶衍生物1-环己基尿嘧啶中三重态布居动力学的直接观测
J Phys Chem Lett. 2015 Nov 5;6(21):4404-9. doi: 10.1021/acs.jpclett.5b01901. Epub 2015 Oct 23.
9
[Optical properties and molecular structure of nucleic acids and their components. IV. Infrared spectra and molecular structure of uracil and its derivatives].[核酸及其组分的光学性质和分子结构。IV. 尿嘧啶及其衍生物的红外光谱和分子结构]
Biofizika. 1966;11(5):753-61.
10
Quantum-mechanical study on the photodimerization of aromatic molecules.
J Theor Biol. 1965 Nov;9(3):357-65. doi: 10.1016/0022-5193(65)90037-8.

引用本文的文献

1
Unveiling the ESIPT Luminescence Mechanism of 4'-N,N-Diethylamino-3-Hydroxyflavone in Ionic Liquid: A Computational Study.揭示离子液体中4'-N,N-二乙氨基-3-羟基黄酮的激发态质子转移发光机制:一项计算研究
Molecules. 2025 Mar 20;30(6):1381. doi: 10.3390/molecules30061381.
2
A Plausible Mechanism of Uracil Photohydration Involves an Unusual Intermediate.尿嘧啶光水合作用的一个合理机制涉及到一种不寻常的中间体。
J Phys Chem Lett. 2022 Aug 4;13(30):7072-7080. doi: 10.1021/acs.jpclett.2c01694. Epub 2022 Jul 28.
3
Photophysical Deactivation Mechanisms of the Pyrimidine Analogue 1-Cyclohexyluracil.
嘧啶类似物 1-环己基尿嘧啶的光物理失活机制。
Molecules. 2021 Aug 27;26(17):5191. doi: 10.3390/molecules26175191.
4
How Does Thymine DNA Survive Ultrafast Dimerization Damage?胸腺嘧啶DNA如何在超快二聚化损伤中存活?
Molecules. 2016 Dec 31;22(1):60. doi: 10.3390/molecules22010060.
5
Time-resolved infrared spectroscopy of the lowest triplet state of thymine and thymidine.胸腺嘧啶和胸腺嘧啶核苷最低三重态的时间分辨红外光谱。
Chem Phys. 2008 May 23;347(1-3):383-392. doi: 10.1016/j.chemphys.2007.10.035.
6
The precursor of the thymine dimer in ice.冰中胸腺嘧啶二聚体的前体。
Proc Natl Acad Sci U S A. 1967 Sep;58(3):895-900. doi: 10.1073/pnas.58.3.895.