Ochoa-Solano A, Romero G, Gitler C
Science. 1967 Jun 2;156(3779):1243-4. doi: 10.1126/science.156.3779.1243.
Model compounds are described for the study of the properties of amino acid side chains in the surface of micelles. Mixed micelles of N-(alpha)- mnyristoyl-L- histidine and cetyltrimethylammonium bromide catalyze the hydrolyses of p-nitrophenyl acetate and p-nitrophenyl caprylate at much higher rates than imidazole or histidinie do. The reaction shows a kinetic behavior similar to that of surface-catalyzed reactions.
描述了用于研究胶束表面氨基酸侧链性质的模型化合物。N-(α)-肉豆蔻酰-L-组氨酸和十六烷基三甲基溴化铵的混合胶束催化对硝基苯乙酸酯和对硝基苯辛酸酯的水解，其速率比咪唑或组氨酸高得多。该反应表现出与表面催化反应相似的动力学行为。
