3-羟基视黄醇在淡水鱼巨魾和孔鳢中的存在。分离与合成。

Occurrence of 3-hydroxyretinol in the freshwater fish Bagarius bagarius and Wallago attu. Isolation and synthesis.

作者信息

Barua A B, Das R C, Verma K

出版信息

Biochem J. 1977 Dec 15;168(3):557-64. doi: 10.1042/bj1680557.

DOI:10.1042/bj1680557

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC1183805/

Abstract

A new chromogen that absorbs maximally at 329 nm was frequently found in the liver oils of the freshwater fish Bagarius bagarius and Wallago attu. It was shown to be a diester of 3-hydroxyretinol. 3-Hydroxyretinol was found to be a metabolite of lutein during the biosynthesis of 3-dehydroretinol in a freshwater fish. A new method for the chemical synthesis of 3-hydroxyretinol from methyl 3-dehydroretinoate is described. The possible pathway for the conversion of lutein into 3-dehydroretinol in vivo is discussed.

摘要

在淡水鱼巨魾和孔鳢的肝油中经常发现一种在329纳米处有最大吸收的新型色原。结果表明它是3-羟基视黄醇的二酯。在淡水鱼3-脱氢视黄醇的生物合成过程中，3-羟基视黄醇被发现是叶黄素的一种代谢产物。本文描述了一种从3-脱氢视黄酸甲酯化学合成3-羟基视黄醇的新方法。文中还讨论了叶黄素在体内转化为3-脱氢视黄醇的可能途径。

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本文引用的文献

1

Anhydrovitamin A2 and rehydrovitamin A2.脱水维生素A2和再水化维生素A2。

J Biol Chem. 1958 Oct;233(4):827-32.

2

Vitamin A2 in Indian fresh-water fish-liver oils.印度淡水鱼鱼肝油中的维生素A2

Biochem J. 1956 Sep;64(1):150-4. doi: 10.1042/bj0640150.

3

A total synthesis of astaxanthin dimethyl ether.虾青素二甲醚的全合成。

J Org Chem. 1967 Jan;32(1):180-4. doi: 10.1021/jo01277a044.

4

Oxidation of zeaxanthin. Isolation and properties of 3-hydroxyretinene.玉米黄质的氧化。3-羟基视黄醛的分离与性质。

Biochem J. 1966 Oct;101(1):250-5. doi: 10.1042/bj1010250.

5

Conversion of lutein into dehydroretinol by the freshwater fish, Saccobranchus fossilis.淡水鱼黄鳝将叶黄素转化为脱氢视黄醇。

Br J Nutr. 1973 Jul;30(1):1-12. doi: 10.1079/bjn19730003.

6

Occurrence and conversion of anhydrolutein into dehydroretinol in a freshwater fish.淡水鱼中脱水叶黄素向脱氢视黄醇的产生与转化

Br J Nutr. 1975 May;33(3):319-27. doi: 10.1079/bjn19750038.

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