Vos C M, Westera G, Schipper D
J Inorg Biochem. 1982 Jun;16(3):245-52. doi: 10.1016/s0162-0134(00)80111-7.
By 13C-nmr on iron-bleomycin preparations, an iron-bleomycin-CO complex is found that loses its CO upon standing, as demonstrated using 14CO. Iron-bleomycin, prepared without rigorous exclusion of oxygen, reacts with CO to a stable diamagnetic iron-bleomycin-CO complex.
通过对博来霉素铁制剂进行碳-13核磁共振分析,发现一种博来霉素铁-一氧化碳复合物,如用碳-14标记的一氧化碳所证实,该复合物在放置时会失去其一氧化碳。在制备博来霉素铁时,若没有严格排除氧气,它会与一氧化碳反应形成一种稳定的抗磁性博来霉素铁-一氧化碳复合物。