Gladkov L L, Solov'ev K N
Mol Biol (Mosk). 1983 Nov-Dec;17(6):1312-7.
The interpretation of the resonance Raman spectra of hemoproteins is given based on the normal coordinate analysis of model compounds (Cu octamethylporphin and Cu octaethylporphin). The correlation between the form of normal vibrations and the sensitivity of vibrational frequencies to the valence and spin state of the Fe atom is discussed.
基于模型化合物(铜八甲基卟啉和铜八乙基卟啉)的简正坐标分析,给出了血蛋白共振拉曼光谱的解释。讨论了简正振动形式与振动频率对铁原子价态和自旋态敏感性之间的相关性。