Cairns T, Siegmund E G
Biomed Mass Spectrom. 1984 Nov;11(11):589-93. doi: 10.1002/bms.1200111107.
One of the cornerstones of an architectural approach adopted by this laboratory in screening vegetables for pesticides and industrial chemicals is the extensive use of element-selective gas chromatographic detectors followed by gas chromatography/mass spectrometry. In this particular case history, a recently introduced European fungicide, iprodione, was thought to be the first reported incidence in mache imported from France. An analytical protocol involving chemical ionization was devised to confirm this finding as well as search for possible potential metabolites.
该实验室在筛选蔬菜中的农药和工业化学品时所采用的一种架构方法的基石之一，是广泛使用元素选择性气相色谱检测器，随后进行气相色谱/质谱分析。在这个具体案例中，一种最近引入欧洲的杀菌剂异菌脲，被认为是首次在从法国进口的马谢菜中被发现。设计了一种涉及化学电离的分析方案来证实这一发现，并寻找可能的潜在代谢物。
