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[与离子半径相关的金属选择性掺入地中海贻贝壳中霰石和方解石的情况]

[Selective incorporation of metals in aragonite and calcite into the shell of Mytilus galloprovincialis in relation to the ionic radius].

作者信息

Cotugno M, Sansone G

出版信息

Boll Soc Ital Biol Sper. 1984 Feb 28;60(2):287-91.

PMID:6712786
Abstract

The Authors assuming as hypothesis that elements beyond Calcium could be included as carbonate according to crystalline structure of Aragonite and Calcite in the shell of Mytilus g. have verified the selective inclusion of Cr, Mg, Zn, Fe, Cu, Cd, Pb in the biocrystals in relation to their ionic radius. Though the ratio of concentrations of these elements in the shell layers: [Me] calcite/[Me] aragonite ( [C]/[A] ) is significatively greater than 1 for Zn and Mg, significatively less than 1 for Cr and Pb and the no-significative distribution of Cu, Fe, Cd do not allow a sure relationship between the ionic radii of Ca and the investigated elements in the process of shell inclusions. However, authors, do not exclude that these elements may be included differently from the relative aragonitic or calcitic crystalline carbonate structures.

摘要

作者假设一个假说,即根据贻贝属贝壳中霰石和方解石的晶体结构,除钙以外的元素可能以碳酸盐形式被纳入其中。作者已经验证了铬、镁、锌、铁、铜、镉、铅在生物晶体中的选择性纳入与其离子半径有关。尽管这些元素在壳层中的浓度比:[Me]方解石/[Me]霰石([C]/[A])对于锌和镁明显大于1,对于铬和铅明显小于1,而铜、铁、镉的分布无明显差异,这使得在贝壳纳入过程中钙的离子半径与所研究元素之间无法确定关系。然而,作者并不排除这些元素可能以不同于相对霰石或方解石晶体碳酸盐结构的方式被纳入。

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