Bradbury J H, Jenkins G A
Carbohydr Res. 1984 Mar 1;126(1):125-56. doi: 10.1016/0008-6215(84)85131-9.
A literature survey of the 13C-n.m.r. chemical-shift data for aqueous solutions of monosaccharides, disaccharides, oligosaccharides, and their methyl derivatives is reported. Analysis of these data reveals a set of empirical rules which may be used in the elucidation of the structure of trisaccharides of known monosaccharide composition, and an example is reported. However, it is not possible to extend the rules to tetrasaccharides and higher saccharides without additional chemical-shift data for related model compounds.
本文报道了对单糖、二糖、寡糖及其甲基衍生物水溶液的13C核磁共振化学位移数据的文献综述。对这些数据的分析揭示了一组经验规则，这些规则可用于阐明已知单糖组成的三糖结构，并给出了一个实例。然而，如果没有相关模型化合物的额外化学位移数据，就不可能将这些规则扩展到四糖及更高的糖类。
