Cook A M, Beilstein P, Hütter R
Int J Environ Anal Chem. 1983;14(2):93-8. doi: 10.1080/03067318308071610.
s-Triazines in waste-water from the synthesis of ametryne (2-(ethylamino)-4-[(l-methylethyl) amino]-6-(methylthio)-1,3,5-triazine) were tentatively identified co-chromatographically by HPLC and by UV-spectra. Alkylated s-triazines (e.g. hydroxyametryne, 4-(ethylamino)-6-(methylthio)-1,3,5-triazine-2(1H)-one, and N-ethylammelide) were isolated by preparative chromatography on a reversed phase support, and were identified by mass spectrometry. Putative cyanuric acid was desalted on activated charcoal and its identity confirmed as the silylated derivative by GLC.
在莠灭净（2-(乙氨基)-4-[(1-甲基乙基)氨基]-6-(甲硫基)-1,3,5-三嗪）合成废水中的均三嗪，通过高效液相色谱（HPLC）和紫外光谱以共色谱法初步鉴定。通过反相载体上的制备色谱法分离出烷基化均三嗪（如羟基莠灭净、4-(乙氨基)-6-(甲硫基)-1,3,5-三嗪-2(1H)-酮和N-乙基三聚氰酸一酰胺），并通过质谱法进行鉴定。假定的氰尿酸在活性炭上脱盐，其身份通过气相色谱法确认为硅烷化衍生物。
