Simmler W
Ecotoxicol Environ Saf. 1982 Oct;6(5):399-412. doi: 10.1016/0147-6513(82)90021-5.
Basic synthetic processes start with more or less inert material of natural origin, both inorganic and organic matter. Process energy is the agent for converting starting material of low reactivity into highly reactive derivatives or elements. The principles of chemical reactions as first steps of synthesis are explained along with the formation of by-products. The second steps of applying separation techniques for purposes of concentration and purification of products desired and of extracting unwanted and harmful products to be reused or eliminated are presented as critical examples. Reuse of by-products within the limits of chemical recycling, as well as degradation or final waste disposal, are shown as third steps. A concept of cleaner technology is outlined as an unachievable aim due to natural limitations of both entropy and energy.
基本的合成过程始于或多或少源自天然的惰性材料,包括无机和有机物质。过程能量是将低反应性的起始原料转化为高反应性衍生物或元素的媒介。阐述了作为合成第一步的化学反应原理以及副产物的形成。作为关键示例,介绍了应用分离技术以浓缩和纯化所需产物以及提取待再利用或消除的不需要和有害产物的第二步。展示了在化学循环范围内副产物的再利用以及降解或最终废物处置作为第三步。由于熵和能量的自然限制,概述了清洁技术的概念,将其作为一个无法实现的目标。