Machata G, Vycudilik W
J Anal Toxicol. 1980 Nov-Dec;4(6):318-21. doi: 10.1093/jat/4.6.318.
Morphine and 6-acetylmorphine in illicit heroin samples can be easily determined by propionylation in aqueous solution (disodium hydrogen phosphate buffer). Heroin, 3-propionylmorphine and 6-acetyl-3-propionylmorphine are separated on methyl-phenylpolysiloxane liquid phases (5% phenyl content). The analytical procedure and the corresponding statistical data are presented together with the retention indices of typical street heroin concomitant drugs. The procedure can also be applied to the analysis of opium preparations and very dilute heroin (morphine) samples.
非法海洛因样品中的吗啡和6-乙酰吗啡可通过在水溶液（磷酸氢二钠缓冲液）中进行丙酰化反应轻松测定。海洛因、3-丙酰吗啡和6-乙酰-3-丙酰吗啡在甲基苯基聚硅氧烷液相（苯基含量5%）上分离。文中给出了分析程序、相应的统计数据以及典型街头海洛因伴随药物的保留指数。该程序也可应用于鸦片制剂和极稀海洛因（吗啡）样品的分析。
