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通过极谱法测定的一些常用氧化还原介质、抑制剂和染料的热力学性质。

The thermodynamic properties of some commonly used oxidation-reduction mediators, inhibitors and dyes, as determined by polarography.

作者信息

Prince R C, Linkletter S J, Dutton P L

出版信息

Biochim Biophys Acta. 1981 Mar 12;635(1):132-48. doi: 10.1016/0005-2728(81)90014-1.

DOI:10.1016/0005-2728(81)90014-1
PMID:7213673
Abstract

The oxidation-reduction midpoint potentials (Em) of the following compounds have been measured in the range of pH from 3 to 12 by polarography: methyl viologen; benzyl viologen; 2-hydroxy-1,4-naphthoquinone; 2-hydroxy-1,4-anthraquinone; N,N,N',N',-tetramethyl-p-phenylenediamine; 2,3,5,6-tetramethyl-p-phenylenediamine; phenazine; N-methylphenazonium methosulfate; N-methylphenazonium sulfonate methosulfate; N-ethylphenazonium ethosulfate; pyocyanine; neutral red; safranin; phenol red; chlorophenol red; cresol red; bromocresol purple; 2,5-dibromo-3-methyl-6-isopropylbenzoquinone and 5-n-undecyl-6-hydroxy-4,7-dioxobenzothiazole. Many of these previously assumed to have a simple behavior in this range have proven to be rather more complicated, and several anomalous observations have been reconciled.

摘要

通过极谱法在pH值3至12的范围内测定了以下化合物的氧化还原中点电位(Em):甲基紫精;苄基紫精;2-羟基-1,4-萘醌;2-羟基-1,4-蒽醌;N,N,N',N'-四甲基对苯二胺;2,3,5,6-四甲基对苯二胺;吩嗪;N-甲基吩嗪硫酸甲酯;N-甲基吩嗪磺酸硫酸甲酯;N-乙基吩嗪硫酸乙酯;绿脓菌素;中性红;番红;酚红;氯酚红;甲酚红;溴甲酚紫;2,5-二溴-3-甲基-6-异丙基苯醌和5-正十一烷基-6-羟基-4,7-二氧代苯并噻唑。这些化合物中许多以前认为在此范围内具有简单行为,结果证明相当复杂,并且一些异常观测结果已得到解释。

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