Nordén B
J Mol Evol. 1978 Oct 6;11(4):313-32. doi: 10.1007/BF01733840.
Stereoselective physical phenomena and their possible importance for the prevalence of D-sugars and L-aminoacids in living matter are reviewed. A classification is presented according to which a selective force provides a microscopic or macroscopic selection depending on its generality when taken over a macrosystem (a 'unitary biosphere' such as the Earth). The microscopic 'selections' are not genuine selections because the final sense of asymmetry is here determined by chance, in other words the initial choice is 'random', while it is 'directed' in the macroscopic selection. Two macroscopic selections appear possible: 1. selection due to an intrinsic energy difference between enantiomorph configurations, 2. selection accomplished by elliptically polarised radiation.
本文综述了立体选择性物理现象及其对生物体内D-糖和L-氨基酸普遍存在的可能重要性。提出了一种分类方法,根据该方法,一种选择力根据其在宏观系统(如地球这样的“单一生物圈”)中的普遍性提供微观或宏观选择。微观“选择”并非真正的选择,因为这里不对称的最终意义是由偶然性决定的,换句话说,初始选择是“随机的”,而在宏观选择中它是“定向的”。两种宏观选择似乎是可能的:1. 由于对映体构型之间的内在能量差异而产生的选择;2. 由椭圆偏振辐射完成的选择。