• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

具有饱和链的磷脂中的六方相:磷脂酰乙醇胺和磷脂酸。

Hexagonal phases in phospholipids with saturated chains: phosphatidylethanolamines and phosphatidic acids.

作者信息

Harlos K, Eibl H

出版信息

Biochemistry. 1981 May 12;20(10):2888-92. doi: 10.1021/bi00513a027.

DOI:10.1021/bi00513a027
PMID:7248255
Abstract

The structure of phospholipids with saturated chains was investigated by differential scanning calorimetry and by X-ray diffraction. It is shown that both phosphatidylethanolamines and phosphatidic acids can exhibit a hexagonal phase at high temperature. The temperature of the transition to the hexagonal phase is dependent on chain length and sodium salt concentration. Increasing the chain length or the sodium salt concentration results in a decrease in the transition temperature. In addition to this transition at high temperature, a calorimetric transition at low temperature, a calorimetric transition at low temperature is detected in some phospholipids.

摘要

通过差示扫描量热法和X射线衍射研究了具有饱和链的磷脂结构。结果表明,磷脂酰乙醇胺和磷脂酸在高温下都能呈现六方相。向六方相转变的温度取决于链长和钠盐浓度。链长或钠盐浓度增加会导致转变温度降低。除了这种高温转变外,在一些磷脂中还检测到低温下的量热转变。

相似文献

1
Hexagonal phases in phospholipids with saturated chains: phosphatidylethanolamines and phosphatidic acids.具有饱和链的磷脂中的六方相:磷脂酰乙醇胺和磷脂酸。
Biochemistry. 1981 May 12;20(10):2888-92. doi: 10.1021/bi00513a027.
2
A calorimetric study of the thermotropic behaviour of 1,2-dipentadecylmethylidene phospholipids.1,2-二戊基亚甲基磷脂热致行为的量热研究。
Biochim Biophys Acta. 1981 Jan 22;640(2):609-18. doi: 10.1016/0005-2736(81)90484-3.
3
Effect of fatty acyl chain length and structure on the lamellar gel to liquid-crystalline and lamellar to reversed hexagonal phase transitions of aqueous phosphatidylethanolamine dispersions.脂肪酰链长度和结构对水性磷脂酰乙醇胺分散体从层状凝胶到液晶以及从层状到反相六方相转变的影响。
Biochemistry. 1989 Jan 24;28(2):541-8. doi: 10.1021/bi00428a020.
4
Different effects of long- and short-chain ceramides on the gel-fluid and lamellar-hexagonal transitions of phospholipids: a calorimetric, NMR, and x-ray diffraction study.长链和短链神经酰胺对磷脂凝胶-流体转变及片层-六方相转变的不同影响:量热法、核磁共振和X射线衍射研究
Biophys J. 2005 May;88(5):3368-80. doi: 10.1529/biophysj.104.057851. Epub 2005 Feb 4.
5
Gel-to-inverted hexagonal (L beta-HII) phase transitions in phosphatidylethanolamines and fatty acid-phosphatidylcholine mixtures, demonstrated by 31P-NMR spectroscopy and x-ray diffraction.通过31P核磁共振光谱和X射线衍射证明,磷脂酰乙醇胺和脂肪酸-磷脂酰胆碱混合物中发生了凝胶态到反相六角形(Lβ-HII)相的转变。
Biochim Biophys Acta. 1982 Aug 25;690(1):117-23. doi: 10.1016/0005-2736(82)90245-0.
6
31P NMR studies of unsonicated aqueous dispersions of neutral and acidic phospholipids. Effects of phase transitions, p2H and divalent cations on the motion in the phosphate region of the polar headgroup.中性和酸性磷脂未超声处理的水分散体的31P核磁共振研究。相变、p2H和二价阳离子对极性头部基团磷酸区域运动的影响。
Biochim Biophys Acta. 1976 Jul 1;436(3):523-40. doi: 10.1016/0005-2736(76)90438-7.
7
Differential scanning calorimetry of chain-melting phase transitions of N-acylphosphatidylethanolamines.N-酰基磷脂酰乙醇胺链熔化相变的差示扫描量热法
Biophys J. 1997 Nov;73(5):2556-64. doi: 10.1016/S0006-3495(97)78284-5.
8
X-ray diffraction study of the polymorphism of hydrated diacyl- and dialkylphosphatidylethanolamines.水合二酰基和二烷基磷脂酰乙醇胺多晶型的X射线衍射研究
Biochemistry. 1984 Jun 5;23(12):2634-44. doi: 10.1021/bi00307a015.
9
Differential scanning calorimetry of thermotropic phase transitions in vitaminylated lipids: aqueous dispersions of N-biotinyl phosphatidylethanolamines.维生素化脂质热致相变的差示扫描量热法:N-生物素化磷脂酰乙醇胺的水分散体
Biophys J. 1994 Jan;66(1):31-9. doi: 10.1016/S0006-3495(94)80761-1.
10
Calorimetric, x-ray diffraction, and spectroscopic studies of the thermotropic phase behavior and organization of tetramyristoyl cardiolipin membranes.四肉豆蔻酰心磷脂膜的热致相行为和结构的量热法、X射线衍射法及光谱学研究
Biophys J. 2007 May 1;92(9):3166-77. doi: 10.1529/biophysj.106.094003. Epub 2007 Feb 9.

引用本文的文献

1
Phosphatidic acid signaling and function in nuclei.磷脂酸信号转导及其在核内的功能。
Prog Lipid Res. 2024 Jan;93:101267. doi: 10.1016/j.plipres.2023.101267. Epub 2023 Dec 26.
2
Small-Angle Neutron Scattering Study of a Phosphatidylcholine-Phosphatidylethanolamine Mixture.磷脂酰胆碱 - 磷脂酰乙醇胺混合物的小角中子散射研究
ACS Omega. 2023 Sep 2;8(37):33755-33762. doi: 10.1021/acsomega.3c04164. eCollection 2023 Sep 19.
3
Phosphatidic Acid Accumulates at Areas of Curvature in Tubulated Lipid Bilayers and Liposomes.在管状脂质双层和脂质体的弯曲区域积累磷脂酸。
Biomolecules. 2022 Nov 17;12(11):1707. doi: 10.3390/biom12111707.
4
Phospholipase Dδ and phosphatidic acid mediate heat-induced nuclear localization of glyceraldehyde-3-phosphate dehydrogenase in Arabidopsis.磷脂酶 Dδ 和磷脂酸介导热诱导的甘油醛-3-磷酸脱氢酶在拟南芥中的核定位。
Plant J. 2022 Nov;112(3):786-799. doi: 10.1111/tpj.15981. Epub 2022 Sep 27.
5
Critical Synergistic Concentration of Lecithin Phospholipids Improves the Antimicrobial Activity of Eugenol against Escherichia coli.卵磷脂磷脂的临界协同浓度提高了丁香酚对大肠杆菌的抗菌活性。
Appl Environ Microbiol. 2017 Oct 17;83(21). doi: 10.1128/AEM.01583-17. Print 2017 Nov 1.
6
Adaptations to High Salt in a Halophilic Protist: Differential Expression and Gene Acquisitions through Duplications and Gene Transfers.嗜盐原生生物对高盐环境的适应性:通过基因复制和基因转移实现的差异表达与基因获得
Front Microbiol. 2017 May 29;8:944. doi: 10.3389/fmicb.2017.00944. eCollection 2017.
7
Red blood cell membrane fluidity in the etiology of multiple sclerosis.多发性硬化症病因中的红细胞膜流动性。
J Membr Biol. 2009 Dec;232(1-3):25-34. doi: 10.1007/s00232-009-9213-1. Epub 2009 Nov 14.
8
Time-resolved x-ray diffraction and calorimetric studies at low scan rates: II. On the fine structure of the phase transitions in hydrated dipalmitoylphosphatidylethanolamine.在低扫描速率下的时间分辨 X 射线衍射和量热研究:II. 水合二棕榈酰磷脂酰乙醇胺相转变的精细结构。
Biophys J. 1992 Mar;61(3):683-93. doi: 10.1016/S0006-3495(92)81873-8.
9
New ordered metastable phases between the gel and subgel phases in hydrated phospholipids.水合磷脂中凝胶相和亚凝胶相之间新的有序亚稳相。
Biophys J. 2001 Apr;80(4):1873-90. doi: 10.1016/S0006-3495(01)76157-7.
10
Surface charge markedly attenuates the nonlamellar phase-forming propensities of lipid bilayer membranes: calorimetric and (31)P-nuclear magnetic resonance studies of mixtures of cationic, anionic, and zwitterionic lipids.表面电荷显著减弱脂质双层膜形成非片层相的倾向:阳离子、阴离子和两性离子脂质混合物的量热法和³¹P核磁共振研究
Biophys J. 2000 Sep;79(3):1455-64. doi: 10.1016/S0006-3495(00)76397-1.